Structural and electronic features of o-phenylenediamido complexes of group 6 metals in different oxidation states

被引：14
|
作者：
Galindo, A
Ienco, A
Mealli, C
机构：
[1] Univ Seville, Dept Quim Inorgan, Seville, Spain
[2] CNR, ICCOM, I-50132 Florence, Italy
来源：
COMMENTS ON INORGANIC CHEMISTRY | 2002年 / 23卷 / 06期
关键词：
diamido/diimino chelates; group; 6; metals; DFT calculations;
D O I：
10.1080/02603590216081
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reported complexes of general formula L4M(phenylenediamido-o), where M is a metal of group 6 in various oxidation states (VI, IV, H and 0), are analyzed. The possible structural deviations from the most symmetric pseudo-octahedral structure (the one with the, chelate in the equatorial plane) are evaluated, case by case, in view of their electronic origin. The analysis is based on systematic DFT calculations and their qualitative MO interpretation based on perturbation theory concepts.
引用
收藏
页码：401 / 416
页数：16
相关论文
共 50 条
  • [21] Heterometallic complexes with cube-type [MTi3N4] cores containing Group 10 metals in a variety of oxidation states
    Martinez-Espada, Noelia
    Mena, Miguel
    Perez-Redondo, Adrian
    Varela-Izquierdo, Victor
    Yelamos, Carlos
    DALTON TRANSACTIONS, 2015, 44 (21) : 9782 - 9794
  • [22] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION METALS .76. ALKYNE COMPLEXES OF RHENIUM IN HIGH OXIDATION-STATES
    HERRMANN, WA
    FELIXBERGER, JK
    KUCHLER, JG
    HERDTWECK, E
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (06): : 876 - 886
  • [23] A DFT Analysis of Structural and Electronic Features of [Mo(CO)6-n(SiX)n] (n=1, 2 and 3, and X=O, S, Se and Te) Complexes
    Sivan, Akhil K.
    Thomas, Jisha Mary
    Christopher Jeyakumar, Thayalaraj
    CHEMISTRYSELECT, 2024, 9 (36):
  • [24] Synthesis, crystal and electronic structure of Cd2PCl2: influence of cation on characteristic structural features of pnictide halides of Group 12 metals
    A. V. Olenev
    O. S. Oleneva
    A. V. Shevelkov
    B. A. Popovkin
    Russian Chemical Bulletin, 2003, 52 : 570 - 575
  • [25] Synthesis, crystal and electronic structure of Cd2PCl2:: influence of cation on characteristic structural features of pnictide halides of Group 12 metals
    Olenev, AV
    Olenva, OS
    Shevelkov, AV
    Popovkin, BA
    RUSSIAN CHEMICAL BULLETIN, 2003, 52 (03) : 570 - 575
  • [26] Tris(amido)tingold complexes in different oxidation states. First structural characterization of a Sn-Au-Au-Sn linear chain
    Findeis, B
    Contel, M
    Gade, LH
    Laguna, M
    Concepcion, M
    Scowen, IJ
    McPartlin, M
    INORGANIC CHEMISTRY, 1997, 36 (11) : 2386 - 2390
  • [27] Structural and Electronic Properties of Polyoxovanadoborates Containing the [V12B18O60] Core in Different Mixed Valence States
    Hermosilla-Ibanez, Patricio
    Munoz-Becerra, Karina
    Paredes-Garcia, Veronica
    Le Fur, Eric
    Spodine, Evgenia
    Venegas-Yazigi, Diego
    INORGANICS, 2015, 3 (03) : 309 - 331
  • [28] METAL-COMPLEXES WITH ANIONIC LIGANDS OF MAIN GROUP-4 ELEMENTS .9. REACTIONS OF TRICHLOROSTANNIDE AND TRICHLOROGERMIDE IONS WITH COMPLEXES OF TRANSITION-METALS IN LOW OXIDATION-STATES
    KRUCK, T
    MOLLS, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1976, 420 (02): : 159 - 176
  • [29] Dangling of electronic properties on different oxidation states in Mn-O system using LCAO, FP-LAPW and inelastic γ-ray scattering
    Suthar, Hukmi Chand
    Meena, Lekhraj
    Ahuja, Ushma
    Pokar, Rushikesh
    Dashora, Alpa
    Heda, N. L.
    Ahuja, B. L.
    SOLID STATE COMMUNICATIONS, 2024, 382
  • [30] MONONUCLEAR NICKEL THIOLATE COMPLEXES CONTAINING NICKEL SITES IN DIFFERENT OXIDATION-STATES - MOLECULAR DEFINITION OF [NI(SC6H4O)2]2- AND [NI(SC6H4O)2]-
    KOCKERLING, M
    HENKEL, G
    CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (04): : 951 - 953
12345