Structural and electronic features of o-phenylenediamido complexes of group 6 metals in different oxidation states

被引：14
|
作者：
Galindo, A
Ienco, A
Mealli, C
机构：
[1] Univ Seville, Dept Quim Inorgan, Seville, Spain
[2] CNR, ICCOM, I-50132 Florence, Italy
来源：
COMMENTS ON INORGANIC CHEMISTRY | 2002年 / 23卷 / 06期
关键词：
diamido/diimino chelates; group; 6; metals; DFT calculations;
D O I：
10.1080/02603590216081
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reported complexes of general formula L4M(phenylenediamido-o), where M is a metal of group 6 in various oxidation states (VI, IV, H and 0), are analyzed. The possible structural deviations from the most symmetric pseudo-octahedral structure (the one with the, chelate in the equatorial plane) are evaluated, case by case, in view of their electronic origin. The analysis is based on systematic DFT calculations and their qualitative MO interpretation based on perturbation theory concepts.
引用
收藏
页码：401 / 416
页数：16
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