Synthesis and Structure of (Rb0.50Ba0.25)[UO2(CH3COO)3]

被引：9
|
作者：
Serezhkina, L. B. [1 ]
Peresypkina, E. V. [2 ]
Virovets, A. V. [2 ]
Klepov, V. V. [1 ]
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 02期
关键词：
CRYSTAL-STRUCTURES;
D O I：
10.1134/S1063774510020094
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new compound (Rb0.50Ba0.25)[UO2(CH3COO)(3)] is synthesized and its crystal structure is studied by X-ray diffraction. The compound crystallizes in the form of yellow plates belonging to the cubic crystal system. The unit cell parameter a = 17.0367(1) angstrom, V = 4944.89(5) angstrom(3), space group I (4) over bar 3d, Z = 16, and R = 0.0182. The coordination polyhedron of the uranium atom is a hexagonal bipyramid with oxygen atoms of three acetate groups and the uranyl group in the vertices. The crystal chemical formula of the uranium-containing group is AB(3)(01) (A = UO22+, B-01 = CH3COO-). The oxygen atoms of the acetate groups that enter the coordination polyhedron of uranium are bound to barium and rubidium atoms.
引用
收藏
页码：221 / 223
页数：3
相关论文
共 50 条
  • [31] LI, RB PARALLEL TO NO3, CH3COO SYSTEM
    DIOGENOV, GG
    ERLYKOV, AM
    GIMELSHT.VG
    ZHURNAL NEORGANICHESKOI KHIMII, 1974, 19 (07): : 1955 - 1960
  • [32] Synthesis, crystal structure, and IR spectral study of Na[(UO2)(C3H7COO)3] · 0.25H2O and K[(UO2)(C3H7COO)3]
    D. V. Pushkin
    A. V. Vologzhanina
    L. B. Serezhkina
    A. V. Savchenkov
    A. A. Korlyukov
    V. N. Serezhkin
    Russian Journal of Inorganic Chemistry, 2012, 57 : 939 - 944
  • [33] Synthesis, Crystal Structure, and IR Spectral Study of Na[(UO2)(C3H7COO)3]•0.25H2O and K[(UO2)(C3H7COO)3]
    Pushkin, D. V.
    Vologzhanina, A. V.
    Serezhkina, L. B.
    Savchenkov, A. V.
    Korlyukov, A. A.
    Serezhkin, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (07) : 939 - 944
  • [34] Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] · 2H2O
    L. B. Serezhkina
    A. V. Vologzhanina
    N. A. Neklyudova
    V. N. Serezhkin
    M. Yu. Antipin
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1193 - 1196
  • [35] Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] • 2H2O
    Serezhkina, L. B.
    Vologzhanina, A. V.
    Neklyudova, N. A.
    Serezhkin, V. N.
    Antipin, M. Yu.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (08) : 1193 - 1196
  • [36] Synthesis and an X-ray diffraction study of the polynuclear complex Na[(UO2)2(OH)3(CH3COO)2] with bridging acetato and hydroxo groups
    Anisimova, NY
    Gorbunova, YE
    Mikhailov, YN
    Chumaevskii, NA
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2001, 46 (04) : 552 - 555
  • [37] TIME-RESOLVED CHIROPTICAL LUMINESCENCE SPECTRA OF UO2(2+) IN CUBIC NA[UO2(CH3COO)3] CRYSTALS - EVIDENCE FOR CIRCULAR DICHROIC SELF-ABSORPTION
    METCALF, DH
    MORAN, DM
    RICHARDSON, FS
    JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 207 : 62 - 64
  • [38] Crystal structure and IR spectroscopic study of (CN3H6)2[(UO2)2(C2O4)(CH3COO)4]
    Serezhkina, L. B.
    Peresypkina, E. V.
    Neklyudova, N. A.
    Virovets, A. V.
    Serezhkin, V. N.
    CRYSTALLOGRAPHY REPORTS, 2013, 58 (02) : 275 - 279
  • [39] Crystal structure and IR spectroscopic study of (CN3H6)2[(UO2)2(C2O4)(CH3COO)4]
    L. B. Serezhkina
    E. V. Peresypkina
    N. A. Neklyudova
    A. V. Virovets
    V. N. Serezhkin
    Crystallography Reports, 2013, 58 : 275 - 279
  • [40] SYNTHESIS AND MOLECULAR-STRUCTURE OF [ZN2(CH3COO)3(OCH3)]
    CHANDLER, CD
    FALLON, GD
    WEST, BO
    POLYHEDRON, 1993, 12 (16) : 2001 - 2004
12345