Synthesis and Structure of (Rb0.50Ba0.25)[UO2(CH3COO)3]

被引：9

作者：

Serezhkina, L. B. ^{[1
]}

Peresypkina, E. V. ^{[2
]}

Virovets, A. V. ^{[2
]}

Klepov, V. V. ^{[1
]}

机构：

[1] Samara State Univ, Samara 443011, Russia

[2] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 02期

关键词：

CRYSTAL-STRUCTURES;

D O I：

10.1134/S1063774510020094

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new compound (Rb0.50Ba0.25)[UO2(CH3COO)(3)] is synthesized and its crystal structure is studied by X-ray diffraction. The compound crystallizes in the form of yellow plates belonging to the cubic crystal system. The unit cell parameter a = 17.0367(1) angstrom, V = 4944.89(5) angstrom(3), space group I (4) over bar 3d, Z = 16, and R = 0.0182. The coordination polyhedron of the uranium atom is a hexagonal bipyramid with oxygen atoms of three acetate groups and the uranyl group in the vertices. The crystal chemical formula of the uranium-containing group is AB(3)(01) (A = UO22+, B-01 = CH3COO-). The oxygen atoms of the acetate groups that enter the coordination polyhedron of uranium are bound to barium and rubidium atoms.

引用

页码：221 / 223

页数：3

共 50 条

[1] Synthesis and structure of (Rb0.50Ba0.25)[UO2(CH3COO)3]
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Crystallography Reports, 2010, 55 : 221 - 223
[2] Synthesis and X-ray diffraction study of (Cs0.5Ba0.25)[UO2(CH3COO)3] and Ba0.5[UO2(CH3COO)3]
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[3] Synthesis and X-ray diffraction study of (Cs0.5Ba0.25)[UO2(CH3COO)3] and Ba0.5[UO2(CH3COO)3]
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[4] Crystal Structure of Rb-3[UO2(CH3COO)(3)](2)[UO2(CH3COO)(NCS)(2)(H2O)]
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[6] Synthesis and crystal structure of (NH4)3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)]
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[7] SYNTHESIS AND STUDY OF NH4[UO2(CH3COO)3]
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[8] Synthesis and Crystal Structure of (NH4)3 [UO2(CH3COO)3]2[UO2(CH3 COO)(NCS)2(H2O)]
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[9] Synthesis, structure, and properties of [Be(H2O) 4][UO2(CH3COO)3]2
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[10] Synthesis and structure of [Cr3O(CH3COO)6(H2O)3][UO2 (CH3COO)3] • 3H2O
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RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (10) : 1341 - 1347

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