Synthesis and characterization of two new halo complexes of iodine: (C4H9)4N[I2Br]- and (C4H9)4N[I2Cl]- and theoretical calculations of their structures

被引：2

作者：

Ghammamy, Shahriar ^{[1
,2
]}

Anvarnia, Zhila ^{[1
]}

Jafari, Mahnaz ^{[2
]}

Mehrani, Kheyrollah ^{[1
]}

Tavakol, Hossein ^{[3
]}

Javanshir, Zahra ^{[1
]}

Rezaeibehbahani, Gholamreza ^{[2
]}

机构：

[1] Islamic Azad Univ, Fac Sci, Dept Chem, Ardabil Branch, Ardebil, Iran

[2] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Ghazvin, Iran

[3] Univ Zabol, Fac Sci, Dept Chem, Zabol, Iran

来源：

MAIN GROUP CHEMISTRY | 2009年 / 8卷 / 04期

关键词：

synthesis; halo compounds; main elements; diiodate; characterization;

D O I：

10.1080/10241220903377481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new compounds of iodine: (C4H9)(4)N[I2Br], (C4H9)(4)N[I2Cl], were easily synthesized in a nearly quantitative yield using a direct reaction of I-2 with tetrabutylammonium halide salts (chloride and bromide). The products were separated and characterized by elemental analysis and spectroscopic methods such as: IR, UV/Visible, H-1-NMR, C-13-NMR and Br-81-NMR techniques. They were studied computationally at B3LYP/LANL2DZ level of theory. The optimized structures are in good agreement with the available experimental results. Production of these compounds shows the ability of tetrabutylammonium salts in halide addition to main group elements.

引用

页码：299 / 306

页数：8

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