Synthesis and catalytic activity of organometallic complexes of palladium(II) with bis-phosphine monosulfides towards ethylene/CO copolymerization

被引：32

作者：

Suranna, GP

Mastrorilli, P

Nobile, CF

Keim, W

机构：

[1] Policlin Bari, Ist Chim, I-70126 Bari, Italy

[2] CNR, Ctr Studi Metodol Innovat Sintesi Organ MISO, I-70126 Bari, Italy

[3] Rhein Westfal TH Aachen, Inst Tech Chem & Petrolchem, D-52074 Aachen, Germany

来源：

INORGANICA CHIMICA ACTA | 2000年 / 305卷 / 02期

关键词：

catalysis; copolymerization; palladium complexes; methyl complexes;

D O I：

10.1016/S0020-1693(00)00128-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The neutral and cationic complexes of formula [(CH3)(Cl)Pd((PP)-P-boolean AND(S))] and [(CH3)(CH3CN)Pd((PP)-P-boolean AND(S))]BF4 [(PP)-P-boolean AND(S) = Ph2PCH2P(S)Ph-2 (dppmS), Ph2P(CH2)(2)P(S)Ph-2 (dppeS)] have been synthesized, characterized and tested as catalysts in the alternating copolymerization of ethylene and carbon monoxide. Both neutral and cationic Pd(II) complexes show eta(2)-(P,S) coordination and cationic complexes exhibit moderate activity. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：151 / 156

页数：6

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