The Michaelis-Becker Reaction in Phosphonium and Imidazolium Ionic Liquids

被引:4
|
作者
Vu, Anh P. [2 ]
Shaffer, Erika A. [2 ]
Congiardo, Laura K. Byington [2 ]
Knight, D. Andrew [1 ]
机构
[1] Florida Inst Technol, Dept Chem, Melbourne, FL 32901 USA
[2] Loyola Univ, Dept Chem, New Orleans, LA 70118 USA
基金
美国国家科学基金会;
关键词
Imidazolium; ionic liquid; Michaelis-Becker; phosphonium;
D O I
10.1080/10426500903329252
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Michaelis-Becker reaction was performed in imidazolium ionic liquids using sodium hydroxide as base or sodium dialkylphosphites with good yield and selectivities. The analogous reaction performed in phosphonium ionic liquids resulted in decomposition to phosphine oxides.
引用
收藏
页码:1845 / 1849
页数:5
相关论文
共 50 条
  • [41] Possibilities and limitations in separating Pt(IV) from Pd(II) combining imidazolium and phosphonium ionic liquids
    Papaiconomou, Nicolas
    Svecova, Lenka
    Bonnaud, Celine
    Cathelin, Loic
    Billard, Isabelle
    Chainet, Eric
    DALTON TRANSACTIONS, 2015, 44 (46) : 20131 - 20138
  • [42] Phosphonium-based ionic liquids
    Tsunashima, K.
    Green Energy and Technology, 2015, 172 : 291 - 310
  • [43] Perfluorinated Ammonium and Phosphonium Ionic Liquids
    Alpers, Torben
    Muesmann, Thomas W. T.
    Temme, Oliver
    Christoffers, Jens
    SYNTHESIS-STUTTGART, 2018, 50 (17): : 3531 - 3539
  • [44] Environmental properties of phosphonium, imidazolium and ammonium cation-based ionic liquids as potential lubricant additives
    Oulego, P.
    Blanco, D.
    Ramos, D.
    Viesca, J. L.
    Diaz, M.
    Hernandez Battez, A.
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 272 : 937 - 947
  • [45] Analysis of microwave-assisted heating and water extraction from imidazolium and phosphonium based ionic liquids
    Araya-López, Claudio
    Carrera, Pedro
    Torres, Alejandra
    Pino-Soto, Luis
    Quijada-Maldonado, Esteban
    Merlet, Gastón
    Romero, Julio
    Plaza, Andrea
    Cabezas, René
    Thermochimica Acta, 2022, 714
  • [46] Temperature Dependence of Physicochemical Properties of Imidazolium-, Pyroldinium-, and Phosphonium-Based Ionic Liquids
    AlTuwaim, Mohammad S.
    Alkhaldi, Khaled H. A. E.
    Al-Jimaz, Adel S.
    Mohammad, Abubaker A.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (06): : 1955 - 1963
  • [47] Industrial preparation of phosphonium ionic liquids
    Bradaric, CJ
    Downard, A
    Kennedy, C
    Robertson, AJ
    Zhou, YH
    IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS, 2003, 856 : 41 - 56
  • [48] Industrial preparation of phosphonium ionic liquids
    Bradaric, CJ
    Downard, A
    Kennedy, C
    Robertson, AJ
    Zhou, YH
    GREEN CHEMISTRY, 2003, 5 (02) : 143 - 152
  • [49] Phosphonium acesulfamate based ionic liquids
    Pernak, J
    Stefaniak, F
    Weglewski, J
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (04) : 650 - 652
  • [50] Phosphonium ionic liquids in biorefinery applications
    Schuur, Boelo
    Li, Xiaohua
    Reyhanitash, Ehsan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253