Phase transformation of methane hydrate under high pressure

被引：6

作者：

Sun, Q ^{[1
]}

Duan, TY

Zheng, HF

Ji, JQ

Wu, XY

机构：

[1] Peking Univ, Sch Earth & Space Sci, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Inst Geophys, Beijing 100029, Peoples R China

来源：

JOURNAL OF CHEMICAL PHYSICS | 2005年 / 122卷 / 02期

关键词：

D O I：

10.1063/1.1830411

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In situ Raman spectroscopy is employed to study the phase behavior of methane hydrate at high pressure. The structure 1 of methane hydrate can be maintained up to 950 MPa at 299 K. The transformation of structure I<---->structure H+water+CH4 occurs at 880 MPa and 323 K. The structure H of methane hydrate, however, decomposes to methane and water at 960 MPa and 348 K. The initiation mechanism of methane hydrate sI is also discussed. (C) 2005 American Institute of Physics.

引用

页数：3

共 50 条

[31] Phase transformation in nanocrystals under pressure
Jiang, JZ
[J]. HIGH PRESSURE EFFECTS IN CHEMISTRY, BIOLOGY AND MATERIALS SCIENCE, 2002, 208-2 : 175 - 186
[32] Phase transformation in hexagonal ErMnO3 under high pressure
Lin, Chuanlong
Liu, Jing
Li, Xiaodong
Li, Yanchun
Chu, Shenqi
Xiong, Lun
Li, Rui
[J]. JOURNAL OF APPLIED PHYSICS, 2012, 112 (11)
[33] PHASE-TRANSFORMATION OF ALLOYS UNDER ACTION OF HIGH-PRESSURE
LAUKHIN, VN
[J]. FIZIKA TVERDOGO TELA, 1974, 16 (09): : 2765 - 2768
[34] Theoretical Analysis of the Structural Phase Transformation in the ZnO Under High Pressure
Verma, Saligram
Jain, Arvind
Nagarch, R. K.
Shah, S.
Kaurav, Netram
[J]. 2ND INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2017), 2018, 1953
[35] SOLID METHANE - CHANGES IN PHASE UNDER PRESSURE
STEVENSON, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1957, 27 (03): : 656 - 658
[36] The effect of elevated methane pressure on methane hydrate dissociation
Circone, S
Stern, LA
Kirby, SH
[J]. AMERICAN MINERALOGIST, 2004, 89 (8-9) : 1192 - 1201
[37] Experiment on methane hydrate kinetics in a high-pressure transparent autoclave
Huang, Ting
Li, Changjun
Li, Qingping
Ding, Ling
Aman Zachary, M.
[J]. Huagong Jinzhan/Chemical Industry and Engineering Progress, 2020, 39 (07): : 2624 - 2631
[38] In situ Raman spectroscopic study of the dissociation of methane hydrate at high pressure
Sun, Q.
Zheng, H. F.
[J]. APPLIED SPECTROSCOPY, 2006, 60 (09) : 985 - 988
[39] High-pressure Raman study of methane hydrate "filled ice"
Ohtani, T.
Ohno, Y.
Sasaki, S.
Kume, T.
Shimizu, H.
[J]. INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, JOINT AIRAPT-22 AND HPCJ-50, 2010, 215
[40] Experimental Investigation of the Mechanical Properties of Methane Hydrate-Bearing Sediments under High Effective Confining Pressure
Xu, Jialin
Xu, Chengshun
Yoshimoto, Norimasa
Hyodo, Masayuki
Kajiyama, Shintaro
Huang, Linghui
[J]. JOURNAL OF GEOTECHNICAL AND GEOENVIRONMENTAL ENGINEERING, 2022, 148 (03)

← 1 2 3 4 5 →