Remote catalyzation for growth of boron nitride nanotubes by low pressure chemical vapor deposition

被引:21
|
作者
Wang, Liangjie [1 ,2 ]
Li, Taotao [2 ]
Ling, Lin [2 ]
Luo, Jie [1 ,2 ]
Zhang, Kai [2 ]
Xu, Yancui [2 ]
Lu, Huifen [2 ]
Yao, Yagang [2 ]
机构
[1] Shanghai Univ, Coll Sci, Dept Mat Sci & Engn, Shanghai 200444, Peoples R China
[2] Chinese Acad Sci, Univ Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Div Adv Nanomat,Key Lab Nanodevices & Applicat, Suzhou 215123, Peoples R China
基金
中国国家自然科学基金;
关键词
Boron nitride nanotubes; Low pressure chemical vapor deposition; Remote catalysts; High purity; ROPES; FUNCTIONALIZATION;
D O I
10.1016/j.cplett.2016.03.055
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Direct deposition of high purity and quality boron nitride nanotubes (BNNTs) on Si substrate were obtained using low pressure chemical vapor deposition (LPCVD). We find Fe-Mg-O species may act as catalysts for growing BNNTs. This synthesis process conforms to vapor-liquid-solid (VLS) growth mechanism. As-grown BNNTs also show a large optical energy band gap of 6.12 eV, approaching to hexagonal phase BN single crystals. Meanwhile, as-grown BNNTs exhibit an intense UV-emission band located at 345 nm and a weak deep band at 237 nm. Their optoelectronic properties make them have promising for future nanoscale deep-UV light emitting devices. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:27 / 31
页数:5
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