Intermolecular hydrogen•••metal interactions.: The crystal structure of {cis-[PdCl2(TPA)2]}2•H2O, a water-soluble palladium(II) tertiary phosphine complex

被引：35
|
作者：
Alyea, EC [1 ]
Ferguson, G [1 ]
Kannan, S [1 ]
机构：
[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 03期
关键词：
D O I：
10.1039/a706243e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The single-crystal X-ray structural determination of {cis-[PdCl2(TPA)(2)]}(2) . H2O (TPA = 1,3,5-triaza-7-phosphaadamantane) establishes that pairs of cis-[PdCl2(TPA)(2)] molecules are linked about inversion centres by intermolecular Pd ... H ... C three-centre-four-electron interactions (2.86, 3.00 Angstrom for the two independent dimers); the water molecule links these dimers via O-H ... N hydrogen bonds to form infinite chains extending in the c-direction in the crystal lattice.
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页码：345 / 346
页数：2
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