A mixed-valence chloride-bridged (pincer)IrIII-(diene)IrI complex

被引：8

作者：

Pelczar, Elizabeth M. ^{[1
]}

Emge, Thomas J. ^{[1
]}

Goldman, Alan S. ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S0108270107022378

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [2,6-bis(di-tert-butylphosphino)phenyl-1 kappa P-3,C-1,P']di-mu-chlorido-1:2 kappa Cl-4:Cl-(2 eta(4)-cycloocta-2,5-diene)-hydrido- 1 kappa H-diiridium(I,III) hexane hemisolvate, [Ir-2(C8H12)-( C24H43P2)Cl2H]center dot 0.5C(6)H(14) or [((PCP)-P-tBu)IrH(mu(2)-Cl)(2)Ir(COD)]-[ (PCP)-P-tBu is kappa(3)-2,6-((Bu2PCH2)-Bu-t)(2)C6H3 and COD is eta(4)-2,5-cyclooctadiene], is an Ir-III/Ir-I dimer bridged by two chloride ions. The Ir2Cl2 framework is nearly planar, with a dihedral angle of 13.04 (4)degrees between the two Ir centers. The compound was isolated as a hexane hemisolvate. A list of distances found in Ir(PCP) compounds is given.

引用

页码：M323 / M326

页数：4

共 50 条

[41] LUMINESCENCE LIFETIMES IN HALOGEN BRIDGED MIXED-VALENCE METAL-COMPLEXES
WADA, Y
ERA, K
[J]. SOLID STATE COMMUNICATIONS, 1988, 67 (10) : 953 - 956
[42] EVIDENCE FOR A NEW VALENCE-AVERAGED MIXED-VALENCE DIRUTHENIUM COMPLEX
SPREER, LO
ALLAN, CB
MACQUEEN, DB
OTVOS, JW
CALVIN, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) : 2187 - 2188
[43] Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes
Maurer, J
Winter, RF
Sarkar, B
Zális, S
[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2005, 9 (11) : 738 - 749
[44] Molecular mixed-valence cyanide bridged CoIII-FeII complexes
Bernhardt, PV
Bozoglián, F
Macpherson, BP
Martínez, M
[J]. COORDINATION CHEMISTRY REVIEWS, 2005, 249 (17-18) : 1902 - 1916
[45] TWO-DIMENSIONAL POTENTIAL SURFACES FOR BRIDGED MIXED-VALENCE DIMERS
ONDRECHEN, MJ
KO, J
ROOT, LJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (24): : 5919 - 5923
[46] AN ELECTRONIC MECHANISM FOR ELECTRON PAIRING IN ANTIFERROMAGNETIC BRIDGED MIXED-VALENCE SYSTEMS
ONDRECHEN, MJ
GOZASHTI, S
WU, XM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (04): : 3255 - 3261
[47] A MODEL FOR THE INTERVALENCE TRANSFER BAND PROFILE OF BRIDGED MIXED-VALENCE DIMERS
KO, J
ONDRECHEN, MJ
[J]. CHEMICAL PHYSICS LETTERS, 1984, 112 (06) : 507 - 512
[48] MIXED-VALENCE INTERACTIONS IN DI-OXO BRIDGED MANGANESE COMPLEXES
COOPER, SR
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 225 - 225
[49] CHARACTERIZATION OF BINUCLEAR MIXED-VALENCE RUTHENIUM COMPLEXES BRIDGED BY A TETRADENTATE LIGAND
SEDNEY, D
LUDI, A
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 181 (MAR): : 186 - INOR
[50] Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes
Jörg Maurer
Rainer F. Winter
Biprajit Sarkar
Stanislav Záliš
[J]. Journal of Solid State Electrochemistry, 2005, 9 : 738 - 749

← 1 2 3 4 5 →