EXAFS spectroscopy investigation Cu(II) complexes encapsulated in cucurbit[8]uril

被引:2
|
作者
Trubina, S. [1 ]
Erenburg, S. [1 ]
Bausk, N. [1 ]
Nadolinny, V. [1 ]
Bakovets, V. [1 ]
Dolgovesova, I. [1 ]
Mitkina, T. [1 ]
机构
[1] RAS, SB, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
关键词
SUPRAMOLECULAR CHEMISTRY;
D O I
10.1088/1742-6596/190/1/012128
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
This work describes EXAFS (extended X-ray absorption fine structure), XANES (X-ray absorption near edge structure) investigation into inclusion compounds of Cu(II) complexes: Cu(acac)(2); [Cu(en)(2)(H2O)(2)](2+); [Cu(cyclam)](2+) in macrocyclic cavitand cucurbit[8]uril at different stages of preparation and heat treatment in hydrogen atmosphere. The structure and composition of the nearest environment of copper atoms have been characterized; the interatomic distances and coordination numbers have been determined.
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页数:4
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