EXAFS spectroscopy investigation Cu(II) complexes encapsulated in cucurbit[8]uril

被引：2

作者：

Trubina, S. ^{[1
]}

Erenburg, S. ^{[1
]}

Bausk, N. ^{[1
]}

Nadolinny, V. ^{[1
]}

Bakovets, V. ^{[1
]}

Dolgovesova, I. ^{[1
]}

Mitkina, T. ^{[1
]}

机构：

[1] RAS, SB, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

14TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS14), PROCEEDINGS | 2009年 / 190卷

关键词：

SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1088/1742-6596/190/1/012128

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

This work describes EXAFS (extended X-ray absorption fine structure), XANES (X-ray absorption near edge structure) investigation into inclusion compounds of Cu(II) complexes: Cu(acac)(2); [Cu(en)(2)(H2O)(2)](2+); [Cu(cyclam)](2+) in macrocyclic cavitand cucurbit[8]uril at different stages of preparation and heat treatment in hydrogen atmosphere. The structure and composition of the nearest environment of copper atoms have been characterized; the interatomic distances and coordination numbers have been determined.

引用

页数：4

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