A Luminescent Eight-Coordinated 2D Cd(II) Framework Material with Flexible Multi-Carboxylate Ligand

被引：5

作者：

Liu, Jian-Qiang ^{[1
]}

Wu, Jian ^{[2
]}

Wu, Tie ^{[1
]}

机构：

[1] Guangdong Med Univ, Coll Pharm, Dongwan, Peoples R China

[2] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning, Guangxi, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2010年 / 40卷 / 04期

关键词：

Cd(II) complex; helical structure; flexible ligand; luminescence; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; METAL; CONSTRUCTION; CADMIUM(II); COMPLEXES;

D O I：

10.1080/15533171003766378

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer of Cd(II), viz., [Cd(ODPA)[image omitted] 2CH3CH2OH[image omitted]2H2O]n (H4ODPA = 2,2',3,3'-oxydiphthalic acid) (1), has been synthesized and structurally characterized by X-ray diffraction. The structure determination reveals that 1 has a 2D network, where each Cd(II) exhibits tetragonal antiprism (uncommon eight-coordinated mode) composed by four bisdentate-chelating carboxylic groups of different ODPA ligands. Moreover, three types of metal-ODPA helices give a 2D herringbone structural motif. The 2D framework stacked in a staggered manner through the [image omitted]-[image omitted] and hydrogen-bonded interactions to form a 3D porous supramolecular structure. Luminescent property for 1 is also discussed.

引用

页码：231 / 236

页数：6

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