Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex

被引：4

作者：

Sun, Xiao-Peng ^{[1
]}

Tang, Zheng ^{[2
]}

Li, Jiajia ^{[1
]}

Ma, Pengtao ^{[1
]}

Yao, Zi-Shuo ^{[2
]}

Wang, Jingping ^{[1
]}

Niu, Jingyang ^{[1
]}

Tao, Jun ^{[2
]}

机构：

[1] Henan Univ, Henan Key Lab Polyoxometalate Chem, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China

[2] Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ, Sch Chem & Chem Engn, Liangxiang Campus, Beijing 102488, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 10期

基金：

中国国家自然科学基金;

关键词：

LIGAND ELECTRON-TRANSFER; SPIN-CROSSOVER; ROOM-TEMPERATURE; MAGNETIC BISTABILITY; THERMAL HYSTERESIS; REDOX ACTIVITY; STATE; TRANSITION; SEMIQUINONE; MODULATION;

D O I：

10.1021/acs.inorgchem.1c03898

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests

引用

页码：4240 / 4245

页数：6

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