CuII-catalysed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with a chiral ferrocene-derived P,N-ligand

被引：9
|
作者：
Bdiri, Bilel [1 ]
Dai, Li [2 ]
Zhou, Zhi-Ming [1 ,3 ]
机构：
[1] Beijing Inst Technol, Sch Chem Engn & Environm, R&D Ctr Pharmaceut, 5th Zhongguancun South St, Beijing 100081, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, 1 North 2nd St, Beijing 100190, Peoples R China
[3] Beijing Inst Technol, State Key Lab Explos Sci & Technol, 5th Zhongguancun South St, Beijing 100081, Peoples R China
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 25期
关键词：
Pyrrolidine; Enantioselectivity; 1,3-Dipolar cycloaddition; Ferrocene ligand; LIGANDS; PROGRESS;
D O I：
10.1016/j.tetlet.2017.05.044
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A ferrocene-derived P,N-heterodonor ligand was effectively used in a Cu(OAc)2 center dot H2O-catalysed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with maleate derivatives, affording cycloadducts with high yields (up to 96%), diastereoselectivities (>99 dr), and enantioselectivities (up to 99% ee). (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2475 / 2481
页数：7
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