Development of self-healing multifunctional materials

被引:53
|
作者
Guadagno, Liberata [1 ]
Naddeo, Carlo [1 ]
Raimondo, Marialuigia [1 ]
Barra, Giuseppina [1 ]
Vertuccio, Luigi [1 ]
Sorrentino, Andrea [2 ]
Binder, Wolfgang H. [3 ]
Kadlec, Martin [4 ]
机构
[1] Univ Salerno, Dept Ind Engn, Via Giovanni Paolo II 132, I-84084 Fisciano, SA, Italy
[2] Natl Res Council CNR, Inst Polymers Composites & Biomat IPCB, Via Previati 1-C, I-23900 Lecce, Italy
[3] Martin Luther Univ Halle Wittenberg, Fac Nat Sci Chem Phys & Math 2, Div Tech & Macromol Chem, Macromol Chem,Inst Chem, Danckelmann Pl 4, Halle, Germany
[4] VZLU Aerosp Res & Test Estab, Beranovych 130, Prague, Czech Republic
关键词
Nano-structures; Thermosetting resins; Smart materials; Polymer-matrix composites (PMCs); TOUGHENED EPOXY COMPOSITE; RUTHENIUM CATALYSTS; CARBON NANOTUBES; FATIGUE CRACKS; BEHAVIOR; HYBRID; NANOCOMPOSITES; DELAMINATION; ENHANCEMENT; RETARDATION;
D O I
10.1016/j.compositesb.2017.07.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Reversible hydrogen bonds determined by interaction between epoxy resin and nanocages of polyhedral oligomeric silsesquioxane (POSS) compound have been employed to activate self-healing mechanisms integrated in thermosetting multifunctional materials. The phase composition of the multifunctional resin containing embedded multiwalled carbon nanotubes (MWCNT) can be advantageously exploited to enhance the healing efficiency up to 400%. The presence of MWCNT is responsible of a greater mobility of chains belonging to domains finely interpenetrated in the matrix where the reversible hydrogen bonds can provide enhanced healing efficiency. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:30 / 38
页数:9
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