Optical birefringence of Zn nanoparticles embedded in silica induced by swift heavy-ion irradiation

Zn nanoparticles (NPs) embedded in a silica matrix subjected to irradiation with swift heavy ions of 200 MeV Xe14+ have been found to undergo shape elongation from spheres to prolate-spheroids while maintaining the major axes of the NPs in parallel alignment. The directionally-aligned Zn spheroids enable acquisition of optical properties, such as linear dichroism and birefringence. In this paper, the birefringence of the Zn spheroids was evaluated by the crossed-Nicols (XN) transmittance, where a sample was inserted between a pair of optical polarizers that were set in an orthogonal configuration. Linearly-polarized light aligned by the first polarizer was transformed to an elliptic polarization by the birefringence of the Zn spheroids. The existence of the birefringence was confirmed by the non-zero transmittance of the second polarizer in the orthogonal configuration. The sample irradiated with a fluence of 5.0 x 10(13) ions/cm(2) exhibited a maximum XN transmittance of 2.1% at a photon energy of similar to 4 eV. The XN transmission was observed down to a fluence of 1.0 x 10(12) ions/cm(2), but reduced below the detection limit at a fluence of 1.0 x 10(11) ions/cm(2). The possible application of the elongated Zn NPs as a polarizer with nanometric thickness working in the near-and midultraviolet region is discussed. (C) 2014 Optical Society of America.