A simple, one-pot oxidative esterification of aryl aldehydes through dialkyl acetal using hydrogen peroxide

被引：2
|
作者：
Devarajan, C. [1 ,2 ]
Vijayakumar, V. [3 ]
Ramalingam, C. [1 ]
Vijayaraghavan, R. [4 ]
机构：
[1] VIT Univ, Sch Biosci & Technol, Vellore 632014, Tamil Nadu, India
[2] India Innovat Ctr, FMC India Private Ltd, Bangalore 560022, Karnataka, India
[3] VIT Univ, Ctr Organ & Med Chem, Vellore 632014, Tamil Nadu, India
[4] VIT Univ, Sch Adv Sci, Mat Chem Div, Ctr Excellence Nano Mat, Vellore 632014, Tamil Nadu, India
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2016年 / 42卷 / 06期
关键词：
Aryl aldehyde; Oxidative esterification; Hydrogen peroxide; Dialkyl acetal; OXIDE NANOPARTICLE CATALYSTS; SUPPORTED GOLD NANOPARTICLES; AROMATIC-ALDEHYDES; CARBOXYLIC-ACIDS; ORGANIC SOLVENT; ALCOHOLS; EFFICIENT; ESTERS; CONVERSION; PROTOCOL;
D O I：
10.1007/s11164-015-2408-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and an efficient one-pot procedure has been developed to synthesize various aryl carboxylic esters directly from aryl aldehydes using hydrogen peroxide without any catalyst. The reaction proceeds smoothly at room temperature. A preliminary investigation suggests the formation of dialkyl acetal as an intermediate during the reaction sequence.
引用
收藏
页码：5849 / 5858
页数：10
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