Iron-Catalyzed One-Pot Oxidative Esterification of Aldehydes

被引：130
|
作者：
Wu, Xiao-Feng [1 ]
Darcelli, Christophe [1 ]
机构：
[1] Univ Rennes 1, CNRS, UMR Sci Chim Rennes 6226, Equipe Catalyse & Organomet, F-35042 Rennes, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 2009卷 / 08期
关键词：
Iron; Esterification; Aldehydes; Homogeneous catalysis; Oxidation; FACILE OXIDATION; METHYL-ESTERS; ALCOHOLS; ACIDS; CONVERSION; METHANOL;
D O I：
10.1002/ejoc.200801176
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly efficient, mild, and simple protocol for Fe(ClO4)(3)center dot xH(2)O-catalyzed oxidative esterification of aldehydes was developed. Several aromatic and aliphatic aldehydes reacted with simple primary and secondary alcohols, used as the solvent, smoothly in the presence of an iron salt catalyst (10 mol-%) and hydroperoxide (4 equiv.) as an oxidant to generate the corresponding esters in good to excellent yields. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：1144 / 1147
页数：4
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