AC conductivity and its scaling behavior in lithium and sodium bismuthate glasses

被引:69
|
作者
Murugaraj, R
Govindaraj, G
George, D
机构
[1] Pondicherry Univ, Raman Sch Phys, Pondicherry 605014, India
[2] Rajiv Gandhi Coll Engn & Technol, Dept Phys, Pondicherry 607402, India
关键词
Ac conductivity; electrical properties; bismuthate glasses; universal power law; scaling behavior;
D O I
10.1016/S0167-577X(02)01047-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ac conductivity measurements and its scaling analysis is studied on the new sodium and lithium bismuthate systems xNa(2)O+ (1-x)Bi2O3 and xLi(2)O+(1-x)Bi2O3 for various compositions in the frequency range from 20 Hz to 1 MHz and in the temperature range from 467 to 750 K. The measured electrical relaxation data of these glasses are analysed using Jonscher's universal power law (UPL) and random free energy barrier model (RFEBM). All experimentally known features of the ac conductivity, including its scaling behavior, are explained satisfactorily based on the power law and random free energy barrier model. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1656 / 1661
页数:6
相关论文
共 50 条
  • [31] Structure and ac conductivity of sodium-lead-cadmium metaphosphate glasses
    El Hezzat, M
    Et-tabirou, M
    Montagne, L
    Bekaert, E
    Palavit, G
    Mazzah, A
    Dhamelincourt, P
    MATERIALS LETTERS, 2004, 58 (1-2) : 60 - 66
  • [32] AC conductivity and its scaling behavior in MgO-Li2O-B2O3-Bi2O3 glasses
    Purnima, M.
    Bale, Shashidhar
    Samee, M. A.
    Ahmmad, Shaik Kareem
    Rahman, Syed
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2013, 74 (02) : 189 - 195
  • [33] Dielectric properties and scaling behavior of lithium tungsten phosphate glasses
    Shaaban, M. H.
    JOURNAL OF ELECTROCERAMICS, 2012, 28 (04) : 246 - 255
  • [34] Dielectric properties and scaling behavior of lithium tungsten phosphate glasses
    M. H. Shaaban
    Journal of Electroceramics, 2012, 28 : 246 - 255
  • [35] Dynamics of lithium ions in bismuthate glasses: Influence of strontium ions
    Dutta, A.
    Ghosh, A.
    JOURNAL OF CHEMICAL PHYSICS, 2006, 125 (05):
  • [36] ON AC CONDUCTIVITY IN CHALCOGENIDE GLASSES
    NAGY, P
    CZECHOSLOVAK JOURNAL OF PHYSICS, 1982, 32 (11) : 1255 - 1263
  • [37] AC CONDUCTIVITY OF TELLURITE GLASSES
    ELKHOLY, MM
    ELMALLAWANY, RA
    MATERIALS CHEMISTRY AND PHYSICS, 1995, 40 (03) : 163 - 167
  • [38] INTERPRETATION OF AC CONDUCTIVITY IN GLASSES
    POLLAK, M
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1973, 18 (03): : 361 - 361
  • [39] Polaronic Conductivity and Scaling Behavior of Lithium Iron Phosphate Glass
    Banday, Azeem
    Murugavel, Sevi
    2ND INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2017), 2018, 1953
  • [40] Can ac conductivity data in mixed alkali glasses be explained using scaling functions?
    Kulkarni, AR
    Tandon, RP
    SOLID STATE IONICS: THE SCIENCE AND TECHNOLOGY OF IONS IN MOTION, 2004, : 799 - 809