1,2,4,5-Tetrakis(2-vinylpyridyl)-benzene-dichloromethane (1/2)

被引：2

作者：

Holmes, BT ^{[1
]}

Padgett, CW ^{[1
]}

Pennington, WT ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem, HL Hunter Res Labs, Clemson, SC 29634 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷

关键词：

D O I：

10.1107/S0108270103001276

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C34H26N4.2CH(2)Cl(2), lies about an inversion center. The solvent molecules interact with the benzene molecule both through C-H...N hydrogen bonding to span pyridine N atoms of adjacent vinyl groups, possibly stabilizing the rotational conformation observed, and through a pi interaction between a dichloromethane Cl atom and a pyridyl ring C-C bond of a c-glide-related molecule. The benzene molecules form stacks along the a axis such that two of the four olefin groups are properly oriented for photoreactivity (2+2 cyclodimerization).

引用

页码：O114 / O116

页数：3

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