Green synthesis: Aromatic nitrations in room-temperature ionic liquids

被引:0
|
作者
Handy, ST [1 ]
Egrie, CR [1 ]
机构
[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As one of the least environmentally compatible synthetic methods,. aromatic nitration has attracted a great deal of effort in terms of the design of more benign techniques. Room temperature ionic liquids (RTILs) afford a useful new method for aromatic nitration by using a simple nitrating agent (nitric acid) with a transition metal catalyst. Distillation of the nitration products affords a solvent/catalyst system that can be readily recycled for at least 4 reactions.
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页码:134 / 146
页数:13
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