Uranyl complexes with 1,2-cycloheptanedione dioxime

被引：2
|
作者：
Beirakhov, A. G. [1 ]
Orlova, I. M. [1 ]
Il'in, E. G. [1 ]
Churakov, A. V. [1 ]
Mikhailov, Yu. N. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 10期
关键词：
Uranyl; Coordination Mode; Binuclear Complex; DMSO Molecule; Uranyl Complex;
D O I：
10.1134/S0036023610100098
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Uranyl compounds with 1,2-cycloheptanedione dioxime (heptoxime) have been studied. Partial isomerization of the ligand takes place upon the formation of aqua complexes. The coordination modes of heptoxime in uranyl complexes were established by X-ray crystallography on [(UO(2))(2)(C(7)H(10)N(2)O(2))(2){(CH(3))(2)SO}(3)] single crystals: cis-(E,E)tetradentate chelating bridging and cis-(E,Z)pentadentate chelating bridging.
引用
收藏
页码：1546 / 1551
页数：6
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