Silver-Catalyzed Oxyphosphorylation of Unactivated Alkynes

被引：9

作者：

Liu, Binbin ^{[1
]}

Song, Qingmin ^{[1
]}

Liu, Zhaohong ^{[1
]}

Wang, Zikun ^{[1
]}

机构：

[1] Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 13期

基金：

中国国家自然科学基金;

关键词：

Alkynes; Silver-catalyzed; Hydroazidation; beta-Ketophosphine oxides; Pyrroles; H-PHOSPHINE OXIDES; C-H/P-H; VINYL AZIDES; ONE-POT; TERMINAL ALKYNES; METAL-FREE; AEROBIC OXYPHOSPHORYLATION; BETA-KETOPHOSPHONATES; CHEMICAL-SYNTHESIS; FACILE SYNTHESIS;

D O I：

10.1002/adsc.202100226

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Here, we describe an application of hydroazidation in the instant activation of alkynes for achieving the oxyphosphorylation of unactivated alkynes with diarylphosphinoyl radicals under mild reaction conditions. This reaction provides a method for accessing beta-ketophosphine oxides and phosphorus-containing pyrroles.

引用

页码：3214 / 3219

页数：6

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