Single crystal of a prussian blue analog based on rubidium manganese hexacyanoferrate

被引：23

作者：

Tokoro, Hiroko

Shiro, Motoo

Hashimoto, Kazuhito

Ohkoshi, Shinchi

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Tokyo 1130033, Japan

[2] Univ Tokyo, Sch Sci, Dept Phys, Tokyo 1130033, Japan

[3] Univ Tokyo, Dept Appl Chem, Sch Engn, Tokyo 1130033, Japan

[4] Rigaku Corp, Tokyo, Japan

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 08期

关键词：

crystal structure; prussian blue analog; cyanide-bridged; metal complexes;

D O I：

10.1002/zaac.200700129

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dark brown single crystal of rubidium manganese hexacyanoferrate, Rb0.61Mn[Fe(CN)(6)](0.87)(.)1.7H(2)O, was obtained by the slow diffusion method. X-ray single crystal analysis showed that this compound crystallized in the cubic system of space group Fm mwith cell constants of a = b = c = 10.5354(4) angstrom, Z = 4, and R-1 =z 0.0449. The CN groups bridge octahedral FeC6 and MnN0.87O0.13. Rb and non-coordinated water (so-called zeolitic water) exist in the interstitial sites of the cubic lattice.

引用

页码：1134 / 1136

页数：3

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