Reversible thermosalience of 4-aminobenzonitrile

被引：31
|
作者：
Alimi, Lukman O. [1 ]
van Heerden, Dewald P. [1 ]
Lama, Prem [1 ]
Smith, Vincent J. [1 ]
Barbour, Leonard J. [1 ]
机构：
[1] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7602 Matieland, South Africa
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 48期
基金：
新加坡国家研究基金会;
关键词：
ANISOTROPIC THERMAL-EXPANSION; CRYSTALS;
D O I：
10.1039/c8cc03636e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystals of 4-aminobenzonitrile grown by sublimation undergo reversible thermosalient phase changes during cooling and subsequent heating. Single-crystal diffraction studies have been carried out at 20 K intervals during cooling from 300 to 100 K in order to explain the structural change that occurs.
引用
收藏
页码：6208 / 6211
页数：4
相关论文
共 50 条
  • [21] Influence of Reactant 4-Aminobenzonitrile Inclusion on the Crystal Structure of (Z)-4-(4-oxopent-2-en-2-ylamino)benzonitrile
    Patil, Siddappa A.
    Medina, Phillip A.
    Dever, Seth
    Ziller, Joseph W.
    Fahlman, Bradley D.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2014, 44 (02) : 82 - 88
  • [22] Influence of Reactant 4-Aminobenzonitrile Inclusion on the Crystal Structure of (Z)-4-(4-oxopent-2-en-2-ylamino)benzonitrile
    Siddappa A. Patil
    Phillip A. Medina
    Seth Dever
    Joseph W. Ziller
    Bradley D. Fahlman
    Journal of Chemical Crystallography, 2014, 44 : 82 - 88
  • [23] NORMAL-MODES OF 4-AMINOBENZONITRILE (4-ABN) - A COMPARISON OF PM3 CALCULATIONS WITH EXPERIMENTAL JET-COOLED SPECTROSCOPY
    YU, HP
    JOSLIN, E
    ZAIN, SM
    RZEPA, H
    PHILLIPS, D
    CHEMICAL PHYSICS, 1993, 178 (1-3) : 483 - 491
  • [24] Pressure-induced phase transition of 4-aminobenzonitrile: the formation and enhancement of N-H•••N weak hydrogen bonds
    Dai, Yuxiang
    Qi, Yang
    RSC ADVANCES, 2018, 8 (09): : 4588 - 4594
  • [25] LASER-INDUCED FLUORESCENCE SPECTROSCOPY OF 4-AMINOBENZONITRILE, 4-(N,N-DIMETHYLAMINO)BENZONITRILE, AND THEIR VANDERWAALS COMPLEXES IN A SUPERSONIC JET
    GIBSON, EM
    JONES, AC
    TAYLOR, AG
    BOUWMAN, WG
    PHILLIPS, D
    SANDELL, J
    JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (19): : 5449 - 5455
  • [26] INFLUENCE OF NON-MESOMORPHIC ADDITIVES ON THE PROPERTIES OF LIQUID CRYSTALLINE MATERIALS. II. MIXTURES OF CYANODERIVATIVES MESOGENS WITH 4-AMINOBENZONITRILE
    Bobritskya, E. V.
    Novikov, I. V.
    Alexandrijsky, V. V.
    Volkov, V. V.
    Burmistrov, V. A.
    LIQUID CRYSTALS AND THEIR APPLICATION, 2009, (02): : 39 - 44
  • [27] 4-Aminobenzonitrile grafted carbon nitrides containing electron-deficient and -sufficient moieties for high-performance photosynthesis of hydrogen peroxide
    Zhao, Hanhan
    Jiang, Wenjun
    Ma, Yinhua
    Pei, Liubin
    An, Jiayu
    Zhan, Su
    Zhou, Feng
    CHEMICAL ENGINEERING JOURNAL, 2025, 505
  • [28] Thermally activated internal conversion with 4-(dimethylamino)benzonitrile, 4-(methylamino)benzonitrile, and 4-aminobenzonitrile in alkane solvents. No correlation with intramolecular charge transfer
    Druzhinin, SI
    Demeter, A
    Galievsky, VA
    Yoshihara, T
    Zachariasse, KA
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (40): : 8075 - 8085
  • [29] Excited states of 4-aminobenzonitrile (ABN) and 4-dimethylaminobenzonitrile (DMABN): Time-resolved resonance Raman, transient absorption, fluorescence, and ab initio calculations
    Ma, C
    Kwok, WM
    Matousek, P
    Parker, AW
    Phillips, D
    Toner, WT
    Towrie, M
    JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (14): : 3294 - 3305
  • [30] Microsolvation of the 4-Aminobenzonitrile Cation (ABN plus ) in a Nonpolar Solvent: IR Spectra of ABN plus Ln (L=Ar and N2, n4)
    Schmies, Matthias
    Patzer, Alexander
    Kruppe, Sarah
    Miyazaki, Mitsuhiko
    Ishiuchi, Shun-ichi
    Fujii, Masaaki
    Dopfer, Otto
    CHEMPHYSCHEM, 2013, 14 (04) : 728 - 740
12345