Photocatalytic Synthesis of Substituted Cyclic Carbonate Monomers for Ring-Opening Polymerization

被引：7

作者：

Maquilon, Cristina ^{[1
]}

Della Monica, Francesco ^{[1
]}

Limburg, Bart ^{[1
]}

Kleij, Arjan W. ^{[1
,2
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 16期

关键词：

Cyclic carbonates; Photocatalysis; Ring-opening polymerization; Ruthenium; Trifluoromethyl; ALTERNATING COPOLYMERIZATION; ALIPHATIC POLYCARBONATES; CATALYTIC STRATEGIES; CO2; DIOXIDE; OXETANES; SUGARS; OXIDE; ALLYLAMINES; PRESSURE;

D O I：

10.1002/adsc.202100654

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An operationally mild, ruthenium-based photocatalytic protocol has been developed for the conversion of gamma-mono- and gamma,gamma-disubstituted allyl carbonates in the presence of Umemoto's reagent to afford substituted six-membered cyclic carbonates. Variation and diversification of the carbonate ring substitution provides access to new monomers useful in ring-opening polymerization leading to polycarbonates with potentially tailored properties, as illustrated by comparative experiments using monomers with different pi-stacking capabilities.

引用

页码：4033 / 4040

页数：8

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