Ligand-free palladium catalyzed phosphorylation of aryl iodides

被引:8
|
作者
Nowrouzi, Najmeh [1 ]
Keshtgar, Saba [1 ]
Jahromi, Enayatollah Bahman [1 ]
机构
[1] Persian Gulf Univ, Dept Chem, Fac Sci, Bushehr 75169, Iran
关键词
Palladium; Phosphorylation; Triarylphosphine; Ligand-free; WATER-SOLUBLE PHOSPHINES; CROSS-COUPLING REACTIONS; P BOND FORMATION; NEAT WATER; SECONDARY PHOSPHINES; TERTIARY PHOSPHINES; PHOSPHONIUM SALTS; HECK REACTIONS; P; N LIGANDS; HALIDES;
D O I
10.1016/j.tetlet.2015.12.018
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A reusable ligand-free palladium catalyzed phosphorylation of aryl iodides using PdCl2/tetrabutylammonium bromide is described. Functionalized triarylphosphines were obtained in good to excellent yields in the absence of external reductants and supporting ligands. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:348 / 350
页数:3
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