Atomic layer deposited ultrathin HfO2 and Al2O3 films as diffusion barriers in copper interconnects

被引:29
|
作者
Majumder, Prodyut [1 ]
Katamreddy, Rajesh
Takoudis, Christos
机构
[1] Univ Illinois, Dept Chem Engn, Chicago, IL 60607 USA
[2] Univ Illinois, Dept Bioengn, Chicago, IL 60607 USA
关键词
D O I
10.1149/1.2756633
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Atomic layer deposited ultrathin HfO2 and Al2O3 films were studied as diffusion barriers between Cu and Si substrate. The thermal stability of 3 nm thick HfO2 and Al2O3 films was investigated after annealing at different temperatures for 5 min in N-2. X-ray diffraction analyses and sheet resistance measurements suggest that both barrier films were thermally stable and the formation of Cu3Si started to take place only after annealing at high temperatures. Specifically, our results show that 3 nm thick HfO2 and Al2O3 diffusion barriers break down after annealing in N-2 at 700 and 750 degrees C, respectively. (C) 2007 The Electrochemical Society.
引用
收藏
页码:H291 / H295
页数:5
相关论文
共 50 条
  • [1] Effect of film thickness on the breakdown temperature of atomic layer deposited ultrathin HfO2 and Al2O3 diffusion barriers in copper metallization
    Majumder, Prodyut
    Katamreddy, Rajesh
    Takoudis, Christos
    [J]. JOURNAL OF CRYSTAL GROWTH, 2007, 309 (01) : 12 - 17
  • [2] Energy barriers at interfaces of (100)GaAs with atomic layer deposited Al2O3 and HfO2
    Afanas'ev, V. V.
    Badylevich, M.
    Stesmans, A.
    Brammertz, G.
    Delabie, A.
    Sionke, S.
    O'Mahony, A.
    Povey, I. M.
    Pemble, M. E.
    O'Connor, E.
    Hurley, P. K.
    Newcomb, S. B.
    [J]. APPLIED PHYSICS LETTERS, 2008, 93 (21)
  • [3] Effect of processing conditions on the electrical characteristics of atomic layer deposited Al2O3 and HfO2 films
    Rafi, J. M.
    Zabala, M.
    Beldarrain, O.
    Campabadal, F.
    [J]. DIELECTRICS FOR NANOSYSTEMS 4: MATERIALS SCIENCE, PROCESSING, RELIABILITY, AND MANUFACTURING, 2010, 28 (02): : 213 - 221
  • [4] Electrical properties of atomic layer deposited HfO2/Al2O3 multilayer on diamond
    Liu, Jiangwei
    Liao, Meiyong
    Imura, Masataka
    Oosato, Hirotaka
    Watanabe, Eiichiro
    Koide, Yasuo
    [J]. DIAMOND AND RELATED MATERIALS, 2015, 54 : 55 - 58
  • [5] Reduction of native oxides on InAs by atomic layer deposited Al2O3 and HfO2
    Timm, R.
    Fian, A.
    Hjort, M.
    Thelander, C.
    Lind, E.
    Andersen, J. N.
    Wernersson, L. -E.
    Mikkelsen, A.
    [J]. APPLIED PHYSICS LETTERS, 2010, 97 (13)
  • [6] Optical and laser damage properties of HfO2/Al2O3 thin films deposited by atomic layer deposition
    Zhang, Qinghua
    Pan, Feng
    Luo, Jin
    Wu, Qian
    Wang, Zhen
    Wei, Yaowei
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 659 : 288 - 294
  • [7] Optimized nitridation of Al2O3 interlayers for atomic-layer-deposited HfO2 gate dielectric films
    Park, HB
    Cho, M
    Park, J
    Lee, SW
    Hwang, CS
    Jeongb, J
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (04) : F25 - F29
  • [8] Effect of an inserted Al2O3 passivation layer for atomic layer deposited HfO2 on indium phosphide
    Xu, Qian
    Ding, Yao-Xin
    Zheng, Zhi-Wei
    Ying, Lei-Ying
    Zhang, Bao-Ping
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2021, 36 (12)
  • [9] Nanoindentation investigation of HfO2 and Al2O3 films grown by atomic layer deposition
    Tapily, K.
    Jakes, J. E.
    Stone, D. S.
    Shrestha, P.
    Gu, D.
    Baumgart, H.
    Elmustafa, A. A.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (07) : H545 - H551
  • [10] Defect Assessment and Leakage Control in Atomic Layer Deposited Al2O3 and HfO2 Dielectrics
    Gonzalez, M. B.
    Rafi, J. M.
    Beldarrain, O.
    Zabala, M.
    Campabadal, F.
    [J]. PROCEEDINGS OF THE 2013 SPANISH CONFERENCE ON ELECTRON DEVICES (CDE 2013), 2013, : 277 - 279