A three-dimensional hydrogen-bonded coordination framework:: catena-poly[[[tetraaquairon(II)]-μ-4,4′-bipyridine] benzene-1,4-dicarboxylate]

被引：5
|
作者：
Halder, GJ [1 ]
Kepert, CJ [1 ]
机构：
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536804032192
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, {[Fe(C10H8N2)(H2O)(4)](C8H4O4)}(n) or [Fe(bpy)(H2O)(4)](bdc) (bpy is 4,4'-bipyridine and bdc is benzene-1,4-dicarboxylate), contains one-dimensional chains of Fe-II centres bridged by bpy ligands along the b axis, with the equatorial coordination of four water molecules completing the octahedral coordination. Non-coordinated bdc anions balance the charge of the Fe-II centres and bridge adjacent one-dimensional chains through an extensive hydrogen-bonding network. The compound crystallizes in the centrosymmetric space group P2/c, which defines twofold axes along both the Fe-bpy chains and the bdc anions.
引用
收藏
页码：M113 / M114
页数：2
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