A comparative study of ionic liquid and organic solvent based porous polymer electrolytes

被引：1
|
作者：
Harshlata [1 ]
Mishra, Kuldeep [2 ]
Rai, D. K. [1 ]
机构：
[1] Jaypee Inst Informat Technol, Dept Phys & Mat Sci & Engn, Noida 201309, India
[2] Jaypee Univ, Dept Phys & Mat Sci, Anoopshahr 203390, Bulandshahr, India
来源：
DAE SOLID STATE PHYSICS SYMPOSIUM 2019 | 2020年 / 2265卷
关键词：
D O I：
10.1063/5.0016976
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Gel polymer electrolyte membranes are prepared by immobilizing two different liquid electrolytes of NaBF4 salt in porous Poly(vinylidene fluoride) PVdF membrane. The liquid electrolytes are prepared in two different solvents, 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4) ionic liquid and binary mixture of ethylene carbonate (EC) and diethyl carbonate (DEC). The effect of solvents is investigated using electrochemical impedance spectroscopy, linear sweep voltammetry and dc polarization technique. The ionic conductivity of the electrolyte membrane with ionic liquid solvent is observed better (similar to 4.1 x 10(-4) S cm(-1)) with better electrochemical stability window of similar to 4.8 V.
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页数：4
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