A simple strategy for spirocyclopentannullation of cyclic ketones. Formal total synthesis of (+/-)-acorone

被引：16
|
作者：
Srikrishna, A
Kumar, PP
Viswajanani, R
机构：
[1] Department of Organic Chemistry, Indian Institute of Science
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期
关键词：
D O I：
10.1016/0040-4039(96)00109-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7 via a prochiral precursor constituting a formal total synthesis of (+/-)-acorone (6), are described.
引用
收藏
页码：1683 / 1686
页数：4
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