UV curing of organic-inorganic hybrid coating materials

被引:64
|
作者
Han, Yung-Hoe
Taylor, Alan
Mantle, Michael D.
Knowles, Kevin M.
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] TWI, Cambridge CB1 6AL, England
[3] Univ Cambridge, Dept Chem Engn, Cambridge CB2 3RA, England
关键词
organic-inorganic hybrid material; sol-gel; tetraethoxysilane (TEOS); 3-(trimethoxysilyl)propyl methacrylate (MPTMA); UV curing;
D O I
10.1007/s10971-007-1544-8
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of UV-curing time on the mechanism of interaction between the various precursor phases in a novel sol-gel-derived organic-inorganic hybrid coating material and the resulting mechanical and thermal properties of this material when coated onto substrates in thin film form have been examined using a variety of chemical and physical characterisation methods. Microstructurally, the hybrid coating materials examined were all a single amorphous phase and were all optically transparent. The degree of interaction between the organic and inorganic phases, the scratch behaviour of the coating materials and the thermal stability of the coating materials were all found to depend strongly on the UV curing time. For the particular proportions of inorganic and organic components used to make up this hybrid coating material, an optimum UV curing time of 10 min under a UV intensity of 46.3 mW cm(-2) was found to produce transparent coatings which adhered well to the substrates and which were robust in scratch tests on aluminium and polycarbonate substrates and abrasion tests on polycarbonate substrates.
引用
收藏
页码:111 / 123
页数:13
相关论文
共 50 条
  • [31] Monophasic organic-inorganic hybrid materials.
    Corriu, R
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1998, 1 (02): : 83 - 89
  • [32] Organic-inorganic planar hybrid materials for spasers
    Toropov, Nikita A.
    Kamalieva, Aisylu N.
    Vartanyan, Tigran A.
    NONLINEAR OPTICS AND APPLICATIONS IX, 2015, 9503
  • [33] Toughening of polycarbonate with organic-inorganic hybrid materials
    Zhang, ZY
    Zhao, N
    Wei, W
    Wu, D
    Sun, YH
    POLYMERS & POLYMER COMPOSITES, 2006, 14 (03): : 291 - 300
  • [34] Organic-inorganic hybrid materials processing and applications
    Schmidt, HK
    Mennig, M
    Nonninger, R
    Oliveira, PW
    Schirra, H
    ORGANIC/INORGANIC HYBRID MATERIALS II, 1999, 576 : 395 - 407
  • [35] Organic-Inorganic Hybrid Materials for Photonic Applications
    Shibata, Shuichi
    Yano, Tetsuji
    Segawa, Hiroyo
    IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2008, 14 (05) : 1361 - 1369
  • [36] Hybrid UV-cured organic-inorganic IPNs
    Sangermano, Marco
    Cook, Wayne D.
    Papagna, Simone
    Grassini, Sabrina
    EUROPEAN POLYMER JOURNAL, 2012, 48 (10) : 1796 - 1804
  • [37] Effect of Organic-Inorganic Hybrid Protecting Coating on Concrete
    Guo Ping
    Qiu Qi
    Luo Zhongkuan
    RARE METAL MATERIALS AND ENGINEERING, 2010, 39 : 169 - 172
  • [38] Hybrid organic-inorganic materials on the basis of acrylic monomers and TEOS prepared by simultaneous UV-curing and sol-gel process
    Khrystyna Demydova
    Andriy Horechyy
    Jochen Meier-Haaсk
    Mikhail Malanin
    Liane Häußler
    Manfred Stamm
    Iryna Yevchuk
    Oksana Demchyna
    Journal of Polymer Research, 2020, 27
  • [39] Hybrid organic-inorganic materials on the basis of acrylic monomers and TEOS prepared by simultaneous UV-curing and sol-gel process
    Demydova, Khrystyna
    Horechyy, Andriy
    Meier-Haack, Jochen
    Malanin, Mikhail
    Haeussler, Liane
    Stamm, Manfred
    Yevchuk, Iryna
    Demchyna, Oksana
    JOURNAL OF POLYMER RESEARCH, 2020, 27 (04)
  • [40] Silsesquiazane/organic polymer blends as organic-inorganic hybrid materials
    Kwang Hee Yoo
    Il Won Kim
    Jeong Ho Cho
    Young-Je Kwark
    Fibers and Polymers, 2012, 13 : 1113 - 1119