Synthesis of 20-Deuterated Bacteriochlorophyll-d Homolog and Its 31-Epimerically Controlled Self-aggregation

被引：1

作者：

Shiozaki, Mai ^{[1
]}

Miyanishi, Takuya ^{[1
]}

Tamiaki, Hitoshi ^{[1
]}

机构：

[1] Ritsumeikan Univ, Grad Sch Life Sci, Kusatsu, Shiga 5258577, Japan

来源：

CHEMISTRY LETTERS | 2021年 / 50卷 / 08期

关键词：

Chlorosome; Isotope effec; Photosynthetic light-harvesting antenna; CHLOROBIUM-VIBRIOFORME; CHLOROPHYLL-A; GREEN; RESONANCE; EXCHANGE; CELLS;

D O I：

10.1246/cl.210279

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3(1)-Epimerically pure samples of farnesylated 20-deutero-8-ethyl-12-methyl-bacteriochlorophyll-d were prepared from naturally occurring chlorophyll-a via regioselective 20-deuteration. Compared with the nondeuterated compounds, the semi-synthetic deuterides exhibited slightly blue-shifted Qy bands in their monomeric states, but similarly produced self-aggregates in a J-type fashion, which were dependent on the 31-stereochemistry.

引用

页码：1539 / 1542

页数：4

共 29 条

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[22] Self-aggregation of zinc bacteriochlorophyll-d analog bearing B-ring reduced chlorin and 17-acrylate residue
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[23] Temperature-dependent chlorosomal self-aggregation of bacteriochlorophyll-d analogs with a branched alkyl chain in a single 1-chlorooctane solvent
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[24] Stereoselective self-aggregation of synthetic zinc 31-epimeric bacteriochlorophyll-d analogs possessing a methylene group at the 132-position as models of green photosynthetic bacterial chlorosomes
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[25] Stereoselective self-aggregation of synthetic zinc 31-epimeric bacteriochlorophyll-d analogs possessing a methylene group at the 132-position as models of green photosynthetic bacterial chlorosomes
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[26] Facile 132-methylation of chlorophyll-a derivative and (132R/S)-stereoselective self-aggregation of zinc bacteriochlorophyll-d analogs
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[27] Self-aggregation of Synthetic Zinc Chlorophyll Derivatives Possessing 31-Hydroxy or Methoxy Group and 131-Mono- or Dicyanomethylene Moiety in Nonpolar Organic Solvents as Models of Chlorosomal Bacteriochlorophyll-d Aggregates
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[28] Substituted Methylenation at the 132-Position of a Chlorophyll-a Derivative via Mixed Aldol Condensation, Optical Properties of the Synthetic Bacteriochlorophyll-d Analogs, and Self-aggregation of Their Zinc Complexes†
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[29] Synthesis of homologously pure bacteriochlorophyll-e and f analogues from BChls-c/d via transformation of the 7-methyl to formyl group and self-aggregation of synthetic zinc methyl bacteriopheophorbides-c/d/e/f in non-polar organic solvent
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