Synthesis of 20-Deuterated Bacteriochlorophyll-d Homolog and Its 31-Epimerically Controlled Self-aggregation

被引：1

作者：

Shiozaki, Mai ^{[1
]}

Miyanishi, Takuya ^{[1
]}

Tamiaki, Hitoshi ^{[1
]}

机构：

[1] Ritsumeikan Univ, Grad Sch Life Sci, Kusatsu, Shiga 5258577, Japan

来源：

CHEMISTRY LETTERS | 2021年 / 50卷 / 08期

关键词：

Chlorosome; Isotope effec; Photosynthetic light-harvesting antenna; CHLOROBIUM-VIBRIOFORME; CHLOROPHYLL-A; GREEN; RESONANCE; EXCHANGE; CELLS;

D O I：

10.1246/cl.210279

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3(1)-Epimerically pure samples of farnesylated 20-deutero-8-ethyl-12-methyl-bacteriochlorophyll-d were prepared from naturally occurring chlorophyll-a via regioselective 20-deuteration. Compared with the nondeuterated compounds, the semi-synthetic deuterides exhibited slightly blue-shifted Qy bands in their monomeric states, but similarly produced self-aggregates in a J-type fashion, which were dependent on the 31-stereochemistry.

引用

页码：1539 / 1542

页数：4

共 29 条

[1] Stereoselective Self-Aggregation of 31-Epimerically Pure Amino Analogs of Zinc Bacteriochlorophyll-d in an Aqueous Micelle Solution
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[2] Synthesis of zinc 20-substituted bacteriochlorophyll-d analogs and their self-aggregation
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[3] Self-aggregation of Synthetic 20-O-Substituted Bacteriochlorophyll-d Analogs
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[4] 31-Substituent-dependent Self-aggregation of Bacteriochlorophyll-d Analogs in Aqueous Micelles
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[5] Synthesis of zinc 20-ethenylated bacteriochlorophyll-d analogs and their self-aggregation in an aqueous micelle solution
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[6] 20-Substitution effect on self-aggregation of synthetic zinc bacteriochlorophyll-d analogs
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[8] Determination of 31-stereochemistry in synthetic bacteriochlorophyll-d homologues and self-aggregation of their zinc complexes
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[10] Self-aggregation of 132,132-disubstituted bacteriochlorophyll-d analog
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