Complexation in binary Cd2[Fe(CN)6]-M(II) systems (M = Mn, Co, Ni, Cu, Zn) in gelatin-immobilized cadmium(II) hexacyanoferrates(II)

被引：8

作者：

Mikhailov, OV ^{[1
]}

Tatarintseva, TB ^{[1
]}

Naumkina, NI ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 05期

关键词：

COORDINATION-COMPOUNDS;

D O I：

10.1023/A:1023623817806

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexation processes that occur between cadmium(II) hexacyanoferrate(II) (Cd-2[Fe(CN)(6)]) and 3d-metal ions M(II) (M=Mn, Co, Ni, Cu, Zn) in thin gelatin layers with the immobilized cadmium(II) hexacyanoferrates when brought in contact with aqueous solutions of d-metal chlorides are studied. Cd2+ ions were found to be replaced to some extent by M2+ ions of the indicated d metals (except for Mn(II)) and form binuclear (dd)-metal hexacyanoferrates(II). A complete replacement of Cd(II) and formation of M-2[Fe(CN)(6)] was observed in none of the cases.

引用

页码：327 / 334

页数：8

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