Complexation in binary Cd2[Fe(CN)6]-M(II) systems (M = Mn, Co, Ni, Cu, Zn) in gelatin-immobilized cadmium(II) hexacyanoferrates(II)

被引：8

作者：

Mikhailov, OV ^{[1
]}

Tatarintseva, TB ^{[1
]}

Naumkina, NI ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 05期

关键词：

COORDINATION-COMPOUNDS;

D O I：

10.1023/A:1023623817806

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexation processes that occur between cadmium(II) hexacyanoferrate(II) (Cd-2[Fe(CN)(6)]) and 3d-metal ions M(II) (M=Mn, Co, Ni, Cu, Zn) in thin gelatin layers with the immobilized cadmium(II) hexacyanoferrates when brought in contact with aqueous solutions of d-metal chlorides are studied. Cd2+ ions were found to be replaced to some extent by M2+ ions of the indicated d metals (except for Mn(II)) and form binuclear (dd)-metal hexacyanoferrates(II). A complete replacement of Cd(II) and formation of M-2[Fe(CN)(6)] was observed in none of the cases.

引用

页码：327 / 334

页数：8

共 50 条

[1] Complexation in binary Cd2[Fe(CN)6]-M(II) systems (M = Mn, Co, Ni, Cu, Zn) in gelatin-immobilized cadmium(II) hexacyanoferrates(II)
Mikhajlov, O.V.
Tatarintseva, T.B.
Naumkina, N.I.
2003, Maik Nauka (29):
[2] Complexation in Binary Cd2[Fe(CN)6]–M(II) Systems (M = Mn, Co, Ni, Cu, Zn) in Gelatin-Immobilized Cadmium(II) Hexacyanoferrates(II)
O. V. Mikhailov
T. B. Tatarintseva
N. I. Naumkina
Russian Journal of Coordination Chemistry, 2003, 29 : 327 - 334
[3] Chemisorption of M(II) ions (M = Mn, Co, Ni, Cu, Zn) on gelatin-immobilized Cd2[Fe(CN)6]complex
Mikhailov, OV
Tatarintseva, TB
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2004, 78 (11): : 1818 - 1821
[4] Electrophilic Substitution Mn(II) → M(II) (M = Co, Ni, Cu, Zn, Cd) in Gelatin-Immobilized Mn2[Fe(CN)6]
O. V. Mikhailov
T. B. Tatarintseva
N. I. Naumkina
V. A. Kolgina
Russian Journal of Coordination Chemistry, 2003, 29 : 630 - 635
[5] Electrophilic substitution Mn(II) → M(II) (M = Co, Ni, Cu, Zn, Cd) in gelatin-immobilized Mn2[Fe(CN)6]
Mikhailov, OV
Tatarintseva, TB
Naumkina, NI
Kolgina, VA
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (09) : 630 - 635
[6] Electrophilic substitution Mn(II) -> M(II) (M = Co, Ni, Cu, Zn, Cd) in gelatin-immobilized Mn2[Fe(CN)6]
Koordinatsionnaya Khimiya, 2003, 29 (09): : 679 - 686
[7] Electrophilic substitution Co(II)→M(II) (M = Mn, Ni, Cu, Zn, Cd) in Co2[Fe(CN)6] gelatin-immobilized matrices
Tatarintseva, TB
Mikhailov, OV
Naumkina, NI
Lygina, TZ
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (02) : 115 - 122
[8] Electrophilic Substitution Co(II)→M(II) (M = Mn, Ni, Cu, Zn, Cd) in Co2[Fe(CN)6] Gelatin-Immobilized Matrices
T. B. Tatarintseva
O. V. Mikhailov
N. I. Naumkina
T. Z. Lygina
Russian Journal of Coordination Chemistry, 2003, 29 : 115 - 122
[9] Chemisorption of M(II) ions (M = Co, Ni, Cu, Zn, and Cd) by gelatin-immobilized Fe(III) hexaferrocyanide (II)
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Tatarintseva, T.B.
Zhurnal Fizicheskoj Khimii, 2003, 77 (12): : 2212 - 2216
[10] Chemisorption of M(II) ions (M = Co, Ni, Cu, Zn, and Cd) by gelatin-immobilized Fe(III) hexaferrocyanide(II)
Mikhailov, OV
Tatarintseva, TB
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