Cyclic α-amino acids via enantioselective metal-catalyzed cascade reactions of dienamides in supercritical carbon dioxide

被引：8
|
作者：
Teoh, E
Jackson, WR
Robinson, AJ [1 ]
机构：
[1] Monash Univ, Ctr Green Chem, Melbourne, Vic 3800, Australia
[2] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2005年 / 58卷 / 01期
关键词：
D O I：
10.1071/CH04219
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly enantioselective conversion of dienamides into cyclic alpha- amino acids can be achieved by a single- pot, tandem hydrogenation - hydroformylation - cyclization - elimination sequence using a single catalyst and supercritical carbon dioxide ( scCO(2)) as the reaction solvent at total pressures significantly lower than those previously reported for related hydrogenation and hydroformylation reactions.
引用
收藏
页码：63 / 65
页数：3
相关论文
共 50 条
  • [21] OXIDATION OF FREE AMINO-ACIDS AND AMINO-ACID-RESIDUES IN PROTEINS BY RADIOLYSIS AND BY METAL-CATALYZED REACTIONS
    STADTMAN, ER
    ANNUAL REVIEW OF BIOCHEMISTRY, 1993, 62 : 797 - 821
  • [22] Derivatization of chiral amino acids in supercritical carbon dioxide
    López, MD
    Blanch, GP
    Herraiz, M
    ANALYTICAL CHEMISTRY, 2004, 76 (03) : 736 - 741
  • [23] Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates
    Shiroodi, Roohollah Kazem
    Gevorgyan, Vladimir
    CHEMICAL SOCIETY REVIEWS, 2013, 42 (12) : 4991 - 5001
  • [24] Transition metal-catalyzed selective oxidation in carbon dioxide.
    Morita, DK
    Pesiri, DR
    Tumas, W
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 369 - INOR
  • [25] Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide
    Brill, Marcel
    Lazreg, Faima
    Cazin, Catherine S. J.
    Nolan, Steven P.
    CARBON DIOXIDE AND ORGANOMETALLICS, 2016, 53 : 225 - 278
  • [26] Transition metal-catalyzed selective oxidation in carbon dioxide.
    Morita, DK
    Pesiri, DR
    Tumas, W
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 134 - INOR
  • [27] Transition metal-catalyzed hydrogenation of carbon dioxide in ionic liquids
    Qadir, Muhammad I.
    Webber, Rodrigo
    Dupont, Jairton
    ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 71, 2019, 71 : 259 - 274
  • [28] Iridium-catalyzed enantioselective hydrogenation of imines in supercritical carbon dioxide
    J Am Chem Soc, 27 (6421-6429):
  • [29] Iridium-catalyzed enantioselective hydrogenation of imines in supercritical carbon dioxide
    Kainz, S
    Brinkmann, A
    Leitner, W
    Pfaltz, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (27) : 6421 - 6429
  • [30] Natural Chiral Ligand Strategy: Metal-Catalyzed Reactions with Ligands Prepared from Amino Acids and Peptides
    Gung, Benjamin W.
    Kubesch, Cole
    Bernstein, Gavriella
    CATALYSTS, 2024, 14 (11)
12345