Octahedral cluster Mo complexes (Bz3NH)3[Mo6OCl13] and (Bz3NH)2[Mo6Cl14] • 2CH3CN:: Synthesis, crystal structure and properties

被引：6

作者：

Kozhomuratova, Zh. S. ^{[1
]}

Naumov, N. G. ^{[1
]}

Naumov, D. Yu. ^{[1
]}

Uskov, E. M. ^{[1
]}

Fedorov, V. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 03期

关键词：

D O I：

10.1134/S1070328407030104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The salts (Bz(3)NH)(3)[Mo6OCl13] (1) and (Bz(3)NH)(2)[Mo6Cll(4)]center dot 2CH3CN (II) were obtained by reacting melted tribenzylamine with cluster Mo compounds. Compound II contains a known cluster anionic complex [Mo6Cl14](2-). Compound I includes novel cluster anionic complex [Mo6OCl13](3-), where one internal Cl atom is replaced by the O atom. Complex II exhibits phosphorescence in a long-wavelength region of visible spectrum.

引用

页码：213 / 221

页数：9

共 50 条

[21] SUBSTITUTION OF SULFUR IN THE MO6CL84+ CLUSTER - SYNTHESIS AND STRUCTURE OF 2 COMPOUNDS WITH THE MO6CL7S3+ CLUSTER UNIT
MICHEL, JB
MCCARLEY, RE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 133 - INOR
[22] Synthesis, crystal structure and thermal properties of [Co(NH 3)5Cl]MO4 (M = Mo, W)
Shusharina E.A.
Khranenko S.P.
Plusnin P.E.
Kardash T.Yu.
Gromilov S.A.
Journal of Structural Chemistry, 2011, 52 (5) : 918 - 923
[23] CRYSTAL-STRUCTURE OF PB2CL6[NH3(CH2)2NH3]
LOFVING, I
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1976, 30 (09): : 715 - 718
[24] NEW COMPLEX OF MOLYBDENUM - MO2CL6(CH3CN)3 - SYNTHESIS AND SUBSTITUTION-REACTIONS
MINISCLOUX, C
MARTINO, G
SAJUS, L
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1973, (7-8): : 2179 - 2183
[25] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIMOLYBDATE, (H3NCH2CH2NH3)MO3O10
KHAN, MI
CHEN, Q
ZUBIETA, J
INORGANICA CHIMICA ACTA, 1993, 213 (1-2) : 325 - 327
[26] Hydrothermal synthesis and characterizaton of [CH3NH3][NH3(CH2)6NH3]H3[P2Mo2W16O62] • H2O
Liu, ZR
Wang, L
Chen, BG
Xu, L
Wang, EB
Xing, Y
Jia, HQ
Lin, YH
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (05): : 772 - 775
[27] SYNTHESIS, CRYSTAL STRUCTURE AND THERMAL PROPERTIES OF [Co(NH3)5Cl]MO4 (M = Mo, W)
Shusharina, E. A.
Khranenko, S. P.
Plusnin, P. E.
Kardash, T. Yu
Gromilov, S. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (05) : 918 - 923
[28] On the interaction of Mo and Mo2 with NH3, C2H4, and C3H6
Lacaze-Dufaure, C
Mineva, T
Russo, N
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2001, 22 (13) : 1557 - 1564
[29] Synthesis and characterization of ethylenediammonium molybdenum thiocomplex [H3NCH2CH2NH3][Mo3S13]
Wang, Y
Chen, JS
Yuan, HM
Shi, Z
Yu, SF
Chen, W
CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (07) : 681 - 688
[30] NORMAL COORDINATE ANALYSIS OP TRINUCLEAR MOLYBDENUM CLUSTER UNIT [Mo3OCl6]2+ IN H[Mo3O（OAc）3Cl6]·3H2O
Lin Chichang Chen GongDepartment of Chemistry
结构化学, 1986, (01) : 14 - 17

← 1 2 3 4 5 →