Octahedral cluster Mo complexes (Bz3NH)3[Mo6OCl13] and (Bz3NH)2[Mo6Cl14] • 2CH3CN:: Synthesis, crystal structure and properties

被引：6
|
作者：
Kozhomuratova, Zh. S. [1 ]
Naumov, N. G. [1 ]
Naumov, D. Yu. [1 ]
Uskov, E. M. [1 ]
Fedorov, V. E. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 03期
关键词：
D O I：
10.1134/S1070328407030104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The salts (Bz(3)NH)(3)[Mo6OCl13] (1) and (Bz(3)NH)(2)[Mo6Cll(4)]center dot 2CH3CN (II) were obtained by reacting melted tribenzylamine with cluster Mo compounds. Compound II contains a known cluster anionic complex [Mo6Cl14](2-). Compound I includes novel cluster anionic complex [Mo6OCl13](3-), where one internal Cl atom is replaced by the O atom. Complex II exhibits phosphorescence in a long-wavelength region of visible spectrum.
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页码：213 / 221
页数：9
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