Study of Ti-P-O based catalysts in oxidative dehydrogenation of N-butane.: Identification of the active phase

被引：0
|
作者：
Marcu, IC
Millet, JMM
Sandulescu, I
机构：
[1] Univ Bucharest, Fac Chim, Dept Technol Chim & Catalyse, Bucharest 030018, Romania
[2] Univ Lyon 1, CNRS, Inst Rech Catalyse, F-69626 Villeurbanne, France
来源：
REVUE ROUMAINE DE CHIMIE | 2004年 / 49卷 / 06期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Eight Ti-P-O catalytic systems with an Ti to P atomic ratio varied between 13:1 and 1:2 were prepared, characterised and tested in the oxidative dehydrogenation of n-butane. Except Ti-2P-O catalyst. which consisted of one phase, namely TiP2O7, the other ones consisted of a two phases, mixture, TiO2 et TiP2O7. It has been shown that all of the catalysts are efficient for n-butane conversion, and that the pyrophosphate phase is responsible for this efficiency. A correlation between the acidity of the solids and their activity was observed.
引用
收藏
页码：573 / 583
页数：11
相关论文
共 50 条
  • [11] The role of molybdenum in Mo-doped V-Mg-O catalysts during the oxidative dehydrogenation of n-butane
    Dejoz, A
    Nieto, JML
    Márquez, F
    Vázquez, MI
    APPLIED CATALYSIS A-GENERAL, 1999, 180 (1-2) : 83 - 94
  • [12] TiP2O7 catalysts characterised by in situ Raman spectroscopy during the oxidative dehydrogenation of n-butane
    Loridant, S
    Marcu, IC
    Bergeret, G
    Millet, JMM
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (20) : 4384 - 4389
  • [13] Semiconductive and redox properties of Ti and Zr pyrophosphate catalysts (TiP2O7 and ZrP2O7).: Consequences for the oxidative dehydrogenation of n-butane
    Marcu, IC
    Millet, JMM
    Herrmann, JM
    CATALYSIS LETTERS, 2002, 78 (1-4) : 273 - 279
  • [14] Semiconductive and Redox Properties of Ti and Zr Pyrophosphate Catalysts (TiP2O7 and ZrP2O7). Consequences for the Oxidative Dehydrogenation of n-Butane
    Ioan-Cezar Marcu
    Jean-Marc M. Millet
    Jean-Marie Herrmann
    Catalysis Letters, 2002, 78 : 273 - 279
  • [15] Bulk and surface structures of V2O5/ZrO2 catalysts for n-butane oxidative dehydrogenation
    Gazzoli, Delia
    De Rossi, Sergio
    Ferraris, Giovanni
    Mattei, Giorgio
    Spinicci, Roberto
    Valigi, Mario
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 310 (1-2) : 17 - 23
  • [16] Oxidative dehydrogenation of i-butane over nanostructured silica-supported NiMoO4 catalysts with low content of active phase
    Zavoianu, R
    Dias, CR
    Soares, APV
    Portela, MF
    APPLIED CATALYSIS A-GENERAL, 2006, 298 : 40 - 49
  • [17] The role and stability of Li2O2 phase in supported LiCl catalyst in oxidative dehydrogenation of n-butane
    Landau, MV
    Gutman, A
    Herskowitz, M
    Shuker, R
    Bitton, Y
    Mogilyansky, D
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 176 (1-2) : 127 - 139
  • [18] MECHANISM AND ACTIVE-SITES FOR N-BUTANE SELECTIVE OXIDATION ON V-P-O CATALYSTS
    SCHRADER, GL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 417 - INOR
  • [19] CO2 promoted oxidative dehydrogenation of n-butane over VOx/MO2ZrO2 (M = Ce or Ti) catalysts
    Raju, Gangadhara
    Reddy, Benjaram M.
    Park, Sang-Eon
    JOURNAL OF CO2 UTILIZATION, 2014, 5 : 41 - 46
  • [20] Oxidative dehydrogenation of n-butane and 1-butene on undoped and K-doped VOx/Al2O3 catalysts
    Nieto, JML
    Concepción, P
    Dejoz, A
    Melo, F
    Knözinger, H
    Vázquez, MI
    CATALYSIS TODAY, 2000, 61 (1-4) : 361 - 367
12345