Oxidative activation of light alkanes on dense ionic oxygen conducting membranes

被引：0
|
作者：
Rebeilleau, M
van Veen, AC
Farrusseng, D
Rousset, JL
Mirodatos, C
Shao, ZP
Xiong, G
机构：
[1] Inst Rech Catalyse, F-69626 Villeurbanne, France
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源：
NATURAL GAS CONVERSION VII | 2004年 / 147卷
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidative dehydrogenation of ethane to ethylene (ODHE) has been studied in a catalytic membrane reactor (CMR) using a dense mixed ionic oxygen and electronic conducting perovskite membrane Ba0.5Sr0.5Co0.8Fe0.2O3-&. At 1080K, an ethylene yield of 66% was obtained with the bare membrane. After Pd cluster deposition, the ethylene yield reached 76% at 1050K. Ni cluster deposition led to a decrease of ethane conversion compared to the bare membrane without changing ethylene selectivity.
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收藏
页码：655 / 660
页数：6
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