Mild and efficient molybdenum-mediated Pauson-Khand-type reaction

被引：33
|
作者：
Adrio, J [1 ]
Rivero, MR [1 ]
Carretero, JC [1 ]
机构：
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 03期
关键词：
D O I：
10.1021/ol047678u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The molybdenum-mediated Pauson-Khand reaction promoted by Mo(CO)(3)(DMF)(3) takes place under very mild conditions in the absence of any promoter. High yields in Pauson-Khand adducts are obtained in the cyclization of a wide variety of functionatized 1,6- and 1,7-enzymes. Enynes bearing electron withdrawing groups at the alkene terminus are particularly good substrates.
引用
收藏
页码：431 / 434
页数：4
相关论文
共 50 条
  • [21] Rhodium-catalyzed intramolecular alkyne-carbodiimide Pauson-Khand-type reaction
    Saito, Takao
    Sugizaki, Katsuya
    Otani, Takashi
    Suyama, Toshiyuki
    ORGANIC LETTERS, 2007, 9 (07) : 1239 - 1241
  • [22] Unique strategy for the assembly of the carbon skeleton of guanacastepene a using an allenic Pauson-Khand-type reaction
    Brummond, KM
    Gao, D
    ORGANIC LETTERS, 2003, 5 (19) : 3491 - 3494
  • [23] Iridium-chiral diphosphine complex catalyzed highly enantioselective pauson-khand-type reaction
    1600, ACS, Washington, DC, USA (122):
  • [24] Iridium-chiral diphosphine complex catalyzed highly enantioselective Pauson-Khand-type reaction
    Shibata, T
    Takagi, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) : 9852 - 9853
  • [25] Iridium-catalyzed enantioselective Pauson-Khand-type reaction of 1,6-enynes
    Shibata, T
    Toshida, N
    Yamasaki, M
    Maekawa, S
    Takagi, K
    TETRAHEDRON, 2005, 61 (42) : 9974 - 9979
  • [26] Total synthesis of (+)-achalensolide based on the Rh(I)-catalyzed allenic Pauson-Khand-type reaction
    Hirose, Toshiyuki
    Miyakoshi, Naoki
    Mukai, Chisato
    JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (03): : 1061 - 1066
  • [27] Rhodium-Catalyzed Pauson-Khand-Type Reaction Using Alcohol as a Source of Carbon Monoxide
    Park, Ji Hoon
    Cho, Yoonhee
    Chung, Young Keun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) : 5138 - 5141
  • [28] New promoters for the molybdenum hexacarbonyl-mediated Pauson-Khand reaction
    Trindade, Alexandre F.
    Petrovski, Zeljko
    Afonso, Carlos A. M.
    ARKIVOC, 2007, : 127 - 141
  • [29] Catalytic Pauson-Khand-type reactions and related carbonylative cycloaddition reactions
    Park, Ji Hoon
    Chang, Kyung-Mi
    Chung, Young Keun
    COORDINATION CHEMISTRY REVIEWS, 2009, 253 (21-22) : 2461 - 2480
  • [30] An allenic Pauson-Khand-type reaction:: A reversal in π-bond selectivity and the formation of seven-membered rings
    Brummond, KM
    Chen, HF
    Fisher, KD
    Kerekes, AD
    Rickards, B
    Sill, PC
    Geib, SJ
    ORGANIC LETTERS, 2002, 4 (11) : 1931 - 1934
12345