Nucleophilic ring-opening of epoxides: trends in β-substituted alcohols synthesis

被引：31

作者：

Fallah-Mehrjardi, Mehdi ^{[1
]}

Kiasat, Ali Reza ^{[2
,3
]}

Niknam, Khodabakhsh ^{[4
]}

机构：

[1] PNU, Dept Chem, Tehran, Iran

[2] Shahid Chamran Univ Ahvaz, Coll Sci, Dept Chem, Ahvaz, Iran

[3] Shahid Chamran Univ Ahvaz, PGGRC, Ahvaz, Iran

[4] Persian Gulf Univ, Fac Sci, Dept Chem, Bushehr 75168, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2018年 / 15卷 / 09期

关键词：

Ring-opening of epoxides; Azidohydrins; Thiocyanohydrins; Cyanohydrins; beta-Aminoalcohols; beta-Nitroalcohols; b-Nitratoalcohols halohydrins; Aminolysis; Alcoholysis; Hydrolysis; Acetolysis; PHASE-TRANSFER CATALYST; CROSS-LINKED POLYACRYLAMIDE; HIGHLY REGIOSELECTIVE CONVERSION; SOLVENT-FREE AMINOLYSIS; EFFICIENT HETEROGENEOUS CATALYST; ACIDIC POLYMERIC CATALYST; QUATERNARY AMMONIUM-SALT; METAL-ORGANIC FRAMEWORK; SCHIFF-BASE COMPLEXES; HYDROXY THIOCYANATES;

D O I：

10.1007/s13738-018-1400-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present review deals with the ring-opening of epoxides by various carbon, nitrogen, oxygen, halogen, and sulfur-containing nucleophiles, which most of the resulting products are versatile intermediates in the synthesis of various biologically active compounds. The regioselectivity and environmentally benign nature of procedures for the synthesis of similar products have been also discussed in detail.

引用

页码：2033 / 2081

页数：49

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