Revealing the charge transfer mechanism in magnetically recyclable ternary g-C3N4/BiOBr/Fe3O4 nanocomposite for efficient photocatalytic degradation of tetracycline antibiotics

Pharmaceutical compounds in water bodies pose hazards to the ecosystem because of their biotoxicity potency. To eradicate such pharmaceutical compounds, a novel g-CN/BiOBr/Fe(3)O(4 )nanocomposites was prepared using a simplistic route and appraised for photodegradation of model tetracycline antibiotics. The g-CN/BiOBr/Fe(3)O(4 )nanocomposites exhibited complete tetracycline degradation in just 60 min exposure of simulated light irradiation, which is 6 times higher than the g-CN. Under the analogous condition, the tetracycline mineralization ability of the g-CN/BiOBr/Fe3O4 nanocomposites was evaluated to be 78% of total organic carbon removal. The superior photocatalytic performance is ascribed to the extended visible light harvesting ability and enhanced charge carrier separation/transfer with impeded recombination rate in light of effective indirect Z-scheme heterojunction construction. Based on band-edge potential and radical trapping studies indicate that h+ > O-center dot(2)- > (OH)-O-center dot are the active species responsible for photodegradation. Furthermore, the ternary nanocomposites are magnetically retrievable and recyclable while retaining their stable photocatalytic performance. This work endows a new perspective on the rational design and construction of magnetically recoverable ternary nano composite for environmental remediation.