t-3-Isopropyl-1-methyl-r-2,c-6-diphenylpiperidin-4-one thiosemicarbazone

被引：11
|
作者：
Sampath, N
Sony, SMM
Ponnuswamy, MN
Nethaji, M
机构：
[1] Univ Madras, Dept Crystallog & Biophys, Madras 600025, Tamil Nadu, India
[2] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S010827010300917X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The piperidine ring in the title compound, C22H28N4S, exhibits a chair conformation. The thiosemicarbazone moiety adopts an extended conformation, and the planar phenyl rings are oriented equatorially with respect to the piperidine ring. Two intermolecular hydrogen bonds involving the S atom form molecular pairs, and the crystal structure is stabilized by weak C-H...pi interactions in addition to van der Waals forces.
引用
收藏
页码：O346 / O348
页数：3
相关论文
共 50 条
  • [41] Molecular and crystal structures of 4′-hydroxy derivative of (3R,6R)-3-methyl-6-isopropyl-2-(4-phenylbenzylidene)cyclohexanone
    L. A. Kutulya
    V. I. Kulishov
    S. V. Shishkina
    A. S. Tolochko
    A. D. Roshal’
    O. V. Shishkin
    Crystallography Reports, 2008, 53 : 455 - 461
  • [42] Crystal structure of (3S,6R)-3-isopropyl-2-[(3R,6S)-6-isopropyl-3-methyl-1-cyclohexenyl]-6-methylcyclohexene, [C6H7(CH3)(C3H7)]2
    Peters, K
    Peters, EM
    Leoni, L
    Fabris, F
    De Lucchi, O
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1999, 214 (02): : 271 - 272
  • [43] Synthesis, spectroscopic (FT-IR, FT-Raman, UV and NMR) and computational studies on 3t-pentyl-2r,6c-diphenylpiperidin-4-one semicarbazone
    Doss, M. Arockia
    Savithiri, S.
    Rajarajan, G.
    Thanikachalam, V.
    Saleem, H.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 148 : 189 - 202
  • [44] Conformational study of some N-acyl-2r, 6c-diphenylpiperidin-4-one oximes using NMR spectra
    Chakkaravarthy, J.
    Muthukumaran, G.
    Pandiarajan, K.
    JOURNAL OF MOLECULAR STRUCTURE, 2008, 889 (1-3) : 297 - 307
  • [45] r-2,c-6-Bis(4-methoxyphenyl)-c-3,t-3-dimethylpiperidin-4-one
    Ponnuswamy, S.
    Mohanraj, V.
    Gayathri, P.
    Thiruvalluvar, A.
    Butcher, R. J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2328 - U2238
  • [46] r-2,c-6-Bis(4-chlorophenyl)-c-3,t-3-dimethylpiperidin-4-one
    Ilango, S. S.
    Ponnuswamy, S.
    Gayathri, P.
    Thiruvalluvar, A.
    Butcher, R. J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2312 - U2090
  • [47] (4R)-3-Hydroxy-7-isopropyl-4-methyl5,6-dihydrobenzofuran-2(4H)-one
    Heinemann, Frank W.
    Herrera, Alberto
    Agrifoglio, Giuseppe
    Dorta, Romano
    Pastran, Jesus
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 0824 - +
  • [48] Conformational study of some N-Nitroso-2r, 6c-diphenylpiperidin-4-one oximes using NMR spectra
    Muthukumaran, G.
    Pandiarajan, K.
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1180 : 285 - 299
  • [49] t-3,t-5-Dimethyl-r-2,c-6-diphenyl-piperidin-4-one
    Balamurugan, S.
    Thiruvalluvar, A.
    Manimekalai, A.
    Jayabharathi, J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O3504 - U3444
  • [50] 1-Formyl-r-2,c-6-bis(4-methoxyphenyl)-t-3,t-5-dimethylpiperidin-4-one
    Kavitha, T.
    Sakthivel, P.
    Ponnuswamy, S.
    Ilango, S. S.
    Ponnuswamy, M. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2818 - U1438
12345