The facile synthesis and characterization of novel cationic metallated and nonmetallated tetrapyridino porphyrazines having different metal centers

被引：12

作者：

Ramirez, C ^{[1
]}

Antonacci, C ^{[1
]}

Ferreira, J ^{[1
]}

Sheardy, RD ^{[1
]}

机构：

[1] Seton Hall Univ, Dept Chem & Biochem, S Orange, NJ 07079 USA

来源：

SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 18期

基金：

美国国家卫生研究院;

关键词：

metallated; nonmetallated; tetracationic porphyrazines;

D O I：

10.1081/SCC-200030591

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A porphyrazine and a series of tetracationic porphyrazines, metallated and nonmetallated, were synthesized. The neutral tetrapyridino porphyrazine was obtained in a yield of 45%. The tetracationic nonmetallated tetraethanoltetrapyridino porphyrazinium iodide was obtained in a yield of 79%. The metallated porphyrazines are (Mn+2, Cu+2, Co+2, Zn+2) = M. M-Tetraethanoltetrapyridino porphyrazinium iodide was obtained in a yield of 78%, 69%, 75%, and 72%, respectively. The porphyrazine and the tetracationic porphyrazines, nonmetallated and metallated, were characterized by elemental analysis, ESI-MS, MALDI-MS, FTIR, and UV-VIS.

引用

页码：3373 / 3379

页数：7

共 27 条

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