Synthesis, Spectral, and Antimicrobial Studies of Nickel(II) Complexes With Nitrogen-Containing Ligands

被引：5

作者：

Omoregie, H. Oluwatola ^{[1
]}

Ojattah, P. ^{[1
]}

Adeleke, O. E. ^{[2
]}

Woods, J. A. O. ^{[1
]}

Capitelli, F. ^{[3
]}

机构：

[1] Univ Ibadan, Dept Chem, Fac Sci, Ibadan, Nigeria

[2] Univ Ibadan, Dept Pharmaceut Microbiol, Ibadan, Nigeria

[3] CNR, Inst Crystallog, I-00016 Monterotondo, Italy

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 04期

关键词：

X-ray; spectral measurements; antimicrobial studies; elemental analysis; conductance; INFRA-RED SPECTRA; 1,10-PHENANTHROLINE; COPPER(II); ADDUCTS;

D O I：

10.1080/15533174.2013.841202

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some nickel(II) complexes of 1,10-phenanthroline and 2,2 '-bipyridine, associated with counterions such as Cl-, NO3-, OAc-, and SO42- have been synthesized and characterized by elemental analysis, conductance, spectral measurements, and antimicrobial studies. The conductance measurement indicates that [Ni(bipy)(2)H2O(NO3)](NO3), [Ni(phen)(2)(H2O)Cl]Cl center dot 3H(2)O center dot CH3OH and [Ni(phen)(3)](NO3)(2).4H(2)O are 1:1 and 1:2 electrolytes, respectively. The infrared and electronic spectral studies are consistent with the adoption of probable six-coordinate octahedral geometry for the complexes. The microbiostatic activity revealed that all the complexes showed pronounced activity against the tested fungi but little or no antibacterial activity. A six-coordinate octahedral geometry was established for [Ni(phen)(2)(H2O)Cl]Cl center dot 3H(2)O center dot CH3OH using X-ray crystallography.

引用

页码：469 / 475

页数：7

共 50 条

[1] RATES OF REACTION OF COMPLEXES OF NICKEL(II) WITH NITROGEN-CONTAINING UNIDENTATE LIGANDS
MELSON, GA
WILKINS, RG
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (10): : 4208 - &
[2] SYNTHESIS AND SPECTRAL STUDIES ON NICKEL(II) COMPLEXES OF AMIDE GROUP-CONTAINING LIGANDS
GARG, BS
KUMAR, V
REDDY, MJ
[J]. TRANSITION METAL CHEMISTRY, 1993, 18 (04) : 364 - 368
[3] CYANIDE COMPLEXES OF IRON(II) WITH NITROGEN-CONTAINING LIGANDS
SERGEEVA, AN
ZUBRITSKAYA, DI
SEMENISHIN, DI
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1975, 20 (07): : 1925 - 1928
[4] Reduction of α,β-unsaturated carbonyl compounds by palladium(II) and nickel(II) complexes having nitrogen-containing ligands
Jana, Partha R.
Sarma, Rupam
Baruah, Jubaraj B.
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 289 (1-2) : 57 - 60
[5] Synthesis, characterization and antimicrobial studies of some macrocyclic ligands and their nickel(II) complexes
Sharma, RC
Khar, VK
[J]. ASIAN JOURNAL OF CHEMISTRY, 1998, 10 (03) : 467 - 471
[6] SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COBALT(II) COMPLEXES SPECTRAL CHARACTRIZATION AND ANTIMICROBIAL STUDIES
Chandra, Sulekh
Pipil, Poonam
Agarwal, Swati
[J]. INTERNATIONAL JOURNAL OF PHARMACEUTICAL SCIENCES AND RESEARCH, 2015, 6 (03): : 1258 - 1265
[7] SPECTRAL STUDIES ON SOME COMPLEXES OF NITROGEN-SULFUR CONTAINING LIGANDS WITH BIS(O,O'DIALKYLDITHIOPHOSPHATO)NICKEL(II)
ALY, AAM
ELSHAHAWY, AS
ELZOHRY, M
MOHAMED, AA
[J]. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1988, (06): : 930 - 932
[8] TERNARY COMPLEXES OF COPPER(II) WITH MIXED ACETYLACETONATE AND NITROGEN-CONTAINING LIGANDS
BAILEY, NA
FENTON, DE
FRANKLIN, MV
HALL, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (06): : 984 - 990
[9] Palladium(II) complexes with polydentate sulfur- and nitrogen-containing ligands
Kolotilov, SV
Goreshnik, EA
Pavlishchuk, VV
Yatsimirskii, KB
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2000, 45 (06) : 868 - 875
[10] NIOBIUM PENTACHLORIDE COMPLEXES WITH NITROGEN-CONTAINING LIGANDS
SURPINA, LV
OSIPOV, OA
KOGAN, VA
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1971, 16 (03): : 685 - &

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