Reduction of α,β-unsaturated carbonyl compounds by palladium(II) and nickel(II) complexes having nitrogen-containing ligands

被引：9

作者：

Jana, Partha R. ^{[1
]}

Sarma, Rupam ^{[1
]}

Baruah, Jubaraj B. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, Assam, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 289卷 / 1-2期

关键词：

N; N-dimethylaminine borane; alpha; beta-unsaturated carbonyl compounds; nickel catalyst; palladium catalyst; reduction reactions;

D O I：

10.1016/j.molcata.2008.04.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic reduction reactions of alpha,beta-unsaturated carbonyl compounds by palladium(II) and nickel(H) complexes with N,N-dimethylammine borane are studied. Palladium and nickel complexes with nitrogen donor ligands such as 2,2 '-bipyridine (bpy) and N,N '-tetramethylethylenediamine are found to be effective catalysts. In the case of [Pd(bpy)Cl-2] selective double bond reduction is observed. Comparative results of palladium(II)- and nickel(II)-catalysed reactions are presented. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：57 / 60

页数：4

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